General, Organic, and Biological Chemistry - 4th edition
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 20, Problem 21P
Interpretation Introduction

(a)

Interpretation:

The structure of an L- aldopentose needs to be drawn.

Concept introduction:

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. Aldopentose is a five-carbon aldehyde sugar.

Expert Solution
Check Mark

Answer to Problem 21P

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  1

Explanation of Solution

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. The absolute configuration of a molecule can be explained using D and L configuration. In D- sugars, the OH group on the bottom chiral center points to the right while in L- sugars, the OH group on the bottom chiral center points to the left. Aldopentose is a five-carbon aldehyde sugar. Xylose, Arabinose and Ribose are few examples.

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  2

Interpretation Introduction

(b)

Interpretation:

The structure of a D- tetrose needs to be drawn.

Concept introduction:

Sugar molecules can name as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. Aldotetrose is a four-carbon aldehyde sugar.

Expert Solution
Check Mark

Answer to Problem 21P

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  3

Explanation of Solution

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. The absolute configuration of a molecule can be explained using D and L configuration. In D- sugars, the OH group on the bottom chiral center points to the right while if L-sugars, the OH group on the bottom chiral center points to the left. Aldotetrose is a four-carbon aldehyde sugar.

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  4

Interpretation Introduction

(c)

Interpretation:

The structure of a five-carbon alditol needs to be drawn.

Concept introduction:

Alditols are polyols. Alditols can be produced by reducing an aldehyde or a ketone group in a monosaccharide.

Expert Solution
Check Mark

Answer to Problem 21P

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  5

Explanation of Solution

Alditols are polyols. Alditols can be produced by reducing an aldehyde or a ketone group in a monosaccharide. In this reduction process, an aldehyde group or a ketone group converts into −CH2OH group. Xylitol is an example of an alditol.

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  6

For an example:

  General, Organic, and Biological Chemistry - 4th edition, Chapter 20, Problem 21P , additional homework tip  7

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Chapter 20 Solutions

General, Organic, and Biological Chemistry - 4th edition

Ch. 20.3 - Prob. 20.3PPCh. 20.3 - Prob. 20.4PPCh. 20.4 - Prob. 20.5PPCh. 20.4 - Prob. 20.6PPCh. 20.4 - Prob. 20.9PCh. 20.4 - Prob. 20.10PCh. 20.5 - Prob. 20.7PPCh. 20.5 - Prob. 20.8PPCh. 20.5 - Lactose contains both an acetal and a hemiacetal....Ch. 20.5 - Prob. 20.12PCh. 20.5 - Prob. 20.13PCh. 20.5 - Prob. 20.14PCh. 20.5 - Prob. 20.15PCh. 20.6 - Prob. 20.16PCh. 20.6 - Prob. 20.17PCh. 20.7 - Prob. 20.18PCh. 20.7 - Prob. 20.19PCh. 20.8 - Prob. 20.20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - Prob. 39PCh. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - Prob. 44PCh. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - What product is formed when each compound is...Ch. 20 - What product is formed when each compound is...Ch. 20 - Prob. 49PCh. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - Prob. 52PCh. 20 - Prob. 53PCh. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - Prob. 56PCh. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - Prob. 70PCh. 20 - Prob. 71PCh. 20 - Prob. 72PCh. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - Prob. 78PCh. 20 - Prob. 79CPCh. 20 - Prob. 80CP
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