The decomposition of dimethyl ether at 504 ° C is ( CH 3 ) 2 O ( g ) → CH 4 ( g ) + H 2 ( g ) + CO ( g ) The following data are partial pressures of dimethyl ether (DME) as a function of time: t = 0 s , P OMG = 312 mmHg; 390s, 264 mmHg; 777s, 224 mmHg; 1195 s, 187 mmHg; 3155 s, 78.5 mmHg. Show that the reaction is first order. What is the value of the rate constant, k ? What is the total gas pressure at 390s? What is the total gas pressure when the reaction has gone to completion? What is the total gas pressure at t =1000s?
The decomposition of dimethyl ether at 504 ° C is ( CH 3 ) 2 O ( g ) → CH 4 ( g ) + H 2 ( g ) + CO ( g ) The following data are partial pressures of dimethyl ether (DME) as a function of time: t = 0 s , P OMG = 312 mmHg; 390s, 264 mmHg; 777s, 224 mmHg; 1195 s, 187 mmHg; 3155 s, 78.5 mmHg. Show that the reaction is first order. What is the value of the rate constant, k ? What is the total gas pressure at 390s? What is the total gas pressure when the reaction has gone to completion? What is the total gas pressure at t =1000s?
Solution Summary: The author explains that in a first order reaction, the rate is linearly proportional to the concentration of the reactant.
The decomposition of dimethyl ether at
504
°
C
is
(
CH
3
)
2
O
(
g
)
→
CH
4
(
g
)
+
H
2
(
g
)
+
CO
(
g
)
The following data are partial pressures of dimethyl ether (DME) as a function of time:
t
=
0
s
,
P
OMG
=
312
mmHg; 390s, 264 mmHg; 777s, 224 mmHg; 1195 s, 187 mmHg; 3155 s, 78.5 mmHg.
Show that the reaction is first order.
What is the value of the rate constant, k?
What is the total gas pressure at 390s?
What is the total gas pressure when the reaction has gone to completion?
Cual es la formula semidesarrollada del 3-metil-1-butino?
2. A graph shown below shows first ionization energies for elements from H to Ne.
First ionization energy/kJ mol
2500
2000
1500
1000
500
T
T
T
T
1
2
3
5
6
7
8
9
10
Atomic number
a) Using arguments of electronic structure, explain why ionization energy of Li is much
lower than that of H.
(2 points)
then dips at O.
b) Using the same arguments, explain why ionization energy increases from B to N, and
(3 points)
Give the name of this compound, including stereochemistry if relevant:
CICH2
CH3
Br
CH₂CH=CH2
Write in the product, including stereochemistry where relevant, for these
reactions. See end of ch. 8, p. 301-303.
1. 03
a) 2-methyl-2-pentene
->
2. Zn, H*
Br2
b) 1-ethylcyclopentene
-->
Chapter 20 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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