1 Matter: Its Properties And Measurement 2 Atoms And The Atomic Theory 3 Chemical Compounds 4 Chemical Reactions 5 Introduction To Reactions In Aqueous Solutions 6 Gases 7 Thermochemistry 8 Electrons In Atoms 9 The Periodic Table And Some Atomic Properties 10 Chemical Bonding I: Basic Concepts 11 Chemical Bonding Ii: Valence Bond And Molecular Orbital Theories 12 Intermolecular Forces: Liquids And Solids 13 Spontaneous Change: Entropy And Gibbs Energy 14 Solutions And Their Physical Properties 15 Principles Of Chemical Equilibrium 16 Acids And Bases 17 Additional Aspects Of Acid–base Equilibria 18 Solubility And Complex-ion Equilibria 19 Electrochemistry 20 Chemical Kinetics 21 Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14 22 Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And Hydrogen 23 The Transition Elements 24 Complex Ions And Coordination Compounds 25 Nuclear Chemistry 26 Structures Of Organic Compounds 27 Reactions Of Organic Compounds expand_more
Chapter Questions expand_more
Problem 1E: In the reaction 2A+BC+3D , reactant A is found to disappear at the rate of 6.2104Ms4 . (a) What is... Problem 2E: From Figure 20-2 estimate the rate of reaction at (a) t= 800 s; (b) the time at which [H2O2]=0.50M . Problem 3E: In the reaction A products, [A] is found to be 0.485 M at t=71.5 s and 0.474 M at t=82.4 s. What is... Problem 4E: In the reaction A products, at t = 0. [A]= 0.1565 M. After 1.00 min. [A]= 0.1498 M. and after 2.00... Problem 5E: In the reaction A products. 4.40 min after the reaction started. [A]= 0.588 M. The rate of reaction... Problem 6E: Refer to Experiment 2 of Table 20.3 and to reaction (20.7) and rate law (208) Exactly 1.00 h after... Problem 7E: For the reaction A+2BC ,the rate of reaction is 1.76103Ms-1 at the time when [A] =0.3580 M. a. What... Problem 8E: If the rate of reaction (20.3) is 5.7104 M s-1 , what is the rate of production of O2(g) from 1.00 L... Problem 9E: In the reaction A(g)B(g)+C(g) , the totalpressure increases while the partial pressure of A(g)... Problem 10E: At 65C , the half-life for the first-order decomposition of N2O2(g) is 2.38 min.... Problem 11E: The initial rate of the reaction A+BC+D is determined for different initial conditions, with the... Problem 12E: For the reaction A+BC+D , the following initial rates of reaction of found. What is the rate law for... Problem 13E Problem 14E: The following data are obtained for the initial rates of reaction in the reaction A+2B+C2D+E a. What... Problem 15E: One of the following statements is true and the other as false regarding the first-order reaction... Problem 16E: One of the following statements true and the other is false regarding the first-order reaction 2AB+C... Problem 17E: The first-order reaction A products has t1/2=180 s. a. What percent of a sample of A remains... Problem 18E: The reaction A products is first order in A. Initially, [A]=0.800M ; and after 54 min, [A]=0.100M .... Problem 19E: The reaction A products is first order A. a. If 1.60g A is allowed to decompose for 38 min, the mass... Problem 20E: In the first-order reaction A products, [A] = 0.816 M initially and 0.632 M after 16.0 mm. What is... Problem 21E: In the first-order reaction A products, it found that 99% of the original amount of reactant A... Problem 22E: The half-life of me radioactive isotope phosphorus-32 is 14.3 days. How long does take Sot a sample... Problem 23E: Acetoacetic acid, CH2COOH2COOH , a reagent in organic synthesis, decomposes in acidic solution,... Problem 24E: The following first-order reaction occurs in CCl4(l) at 45C:N2O5N2O412O2(g) . The rate constant is... Problem 25E: For the reaction A- products, the following data give [A] as a function of time. t = 0s. [A]=... Problem 26E: The decomposition of dimethyl ether at 504C is ( CH3)2O(g)CH4(g)+H2(g)+CO(g) The following data are... Problem 27E: [Hint: There are several of arrivivg at answer for each of the following six questions.] Which of... Problem 28E: [Hint: There are several of arrivivg at answer for each of the following six questions.] What is the... Problem 29E Problem 30E Problem 31E Problem 32E Problem 33E: [Hint: There are several of arrivivg at answer for each of the following six questions.] The... Problem 34E: [Hint: There are several ways of arrivivig at answers for each of the following six questions.] A... Problem 35E Problem 36E Problem 37E: For the reaction A products, the following data were obtained t=0s , [A]=0.715M ; 22 s. 0605 M, 74... Problem 38E Problem 39E: For the reaction A products, the data tabulated below are obtained. Determine the initial rate of... Problem 40E: For the reaction A2B+C , the following data are obtained for [A] as a function of time: t=0min , [A]... Problem 41E: In three different experiments, the following results were obtained for the reaction A produces:... Problem 42E: Ammonia decomposes on the surface of a hot tungsten wire. Following are the half-live that were... Problem 43E Problem 44E: Consider three hypothetical reactions A — products al having the same numerical value of the rate... Problem 45E Problem 46E: If even tiny sped is introduced into a mixture of H2(g) and O2(g) , a highly exothermac explosive... Problem 47E: For me reversible reaction A+BC+D , the enthalpy change of the forward reaction is +21 kJ/mol. The... Problem 48E Problem 49E: By inspection of the reaction profile for the reaction A to D given below, answer the following... Problem 50E: By inspection of the reaction profile for the reaction A to 0 given, answer the following questions.... Problem 51E: The rate constant for the reaction H2(g)+l2(g)2Hl(g) has been determined at the following... Problem 52E: At what temperature will the rate constant for the reaction in Exercise 51 have the value... Problem 53E Problem 54E: The reaction C2H5+OHC2H5OH+I was studied in an ethanol (C2H5OH) solution, and the following rate... Problem 55E: The first-order reaction A products has a half-life, t1/2 of 46.2 min at 25C and 2.6 min at 102C... Problem 56E: For the first-order reaction N2O4(g)2NO2+12O2g t1/2=22.5 h at 20C and 1.5 h at 40C Calculate the... Problem 57E Problem 58E: Concerning the rule of thumb stated r Exercise 57, estimate how much faster cooking occurs in a... Problem 59E: The following statements about catalysis are not stated as carefully as they might be What sight... Problem 60E Problem 61E: What are the similarities and differences between the catalytic activity of platinum metal and of an... Problem 62E: Certain gas-phase reactions on a heterogeneous catalyst are first order at low gas pressures and... Problem 63E: The graph show s the effect of enzyme concentration on the rate of an enzyme reaction. What reaction... Problem 64E: The graph shows the effect of temperature on enzyme activity. Explain why the graph has the general... Problem 65E Problem 66E Problem 67E: The reaction 2NO+2H2N2+2H2O is second order m [NO] and first order in [H2] . A three-step meachanism... Problem 68E: The mechanism proposed for me reaction of H2(g) and I2(g) to from HI(g) consists of a fast step... Problem 69E: The reaction 2NO+Cl22NOCl has rate law: rate of reaction= K[NO]2[Cl2] . Propose a twostep mechanism... Problem 70E: A simplified rate law 1o the reaction 2O2(g)3O2(g) is rate=k[ O 3]2[O2] For this reaction, propose a... Problem 71E Problem 72E: One proposed meachanism for the condensation of propanone, ( CH2)2CO , is as follows: ( CH... Problem 73IAE: Suppose that the reaction r Example 20-8 is first order with a rate constant of 0.12 min-1 .... Problem 74IAE: [A]t as a function of time for the reaction A — products e plotted in the following Use data from... Problem 75IAE: Exactly 300 s after decomposition of H2O2(aq) begin (reaction 20.3), a 5.00 mL of sample is removed... Problem 76IAE: Use the method of Exercise 75 to determine the volume of 0.1000 M KMnO4 required to titrate 5.00 mL... Problem 77IAE Problem 78IAE Problem 79IAE: Hydroxide ion is involved in the mechanism of the following reaction but is not consumed in the... Problem 80IAE: The half-life for the first-order decomposition of nitramide, NH2NO2(aq)N2O(g)+H2O(l) , is 123 min... Problem 81IAE: The decomposition of ethylene oxide at 690 K is monitored by measuring the total gas pressure as a... Problem 82IAE Problem 83IAE: The following data are for the reaction 2 A + B products. Establish the order of this reaction with... Problem 84IAE Problem 85IAE Problem 86IAE Problem 87IAE: The following three-step mechanism has been pro-posed the reaction of chlorine and chloroform.... Problem 88IAE Problem 89IAE Problem 90IAE Problem 91IAE Problem 92IAE Problem 93IAE Problem 94IAE: You want to test the following proposed mechanism for the oxidation of HBr.... Problem 95IAE Problem 96FP: Benzenediazonium chloride decomposes by a first-order reaction in water, yielding N2(g) as one... Problem 97FP: The object is to study the kinetics of the reaction between perioxodisulfate and iodide ions.... Problem 98SAE Problem 99SAE Problem 100SAE: Explain the important distinctions between each paw of terms (a) first-order and second-order... Problem 101SAE Problem 102SAE: A first-order reaction A — products, has a half-life of 75 s, from which we can draw two... Problem 103SAE Problem 104SAE Problem 105SAE: The rate of a chemical reaction generally increases rapidly, even for small increases in... Problem 106SAE: For the reaction A+B2C, which proceeds by a single-step bimolecular elementary process (a)... Problem 107SAE Problem 108SAE Problem 109SAE Problem 110SAE: For me reaction A products the following data are obtained. a. Determine the initial rate of... Problem 111SAE: For the reaction A+2BC+D , the rate law is rate oif reaction =K[A][B]. a. Show that the following... Problem 112SAE Problem 113SAE: If the plot of the reactant concentration versus time is linear, then the order of the reaction (a)... Problem 114SAE Problem 115SAE format_list_bulleted