The approximate half-life for the first order reaction is to be determined. Set I Set II Set III Time, s [A], M Time, s [A], M Time, s [A], M 0 1.00 0 1.00 0 1.00 25 0.78 25 0.75 25 0.80 50 0.61 50 0.50 50 0.67 75 0.47 75 0.25 75 0.57 100 0.37 100 0.00 100 0.50 150 0.22 150 0.40 200 0.14 200 0.33 250 0.08 250 0.29 Concept introduction: Zero-order reaction - for this, rate of reaction is independent of the concentration. And the graph of zero order reaction is- The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant. And half-life is Integral rate law for first order reaction is − and The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant. Integral rate law for second order reaction is − And the graph of second order reaction is-

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Answer 1

Question

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

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Answer 2

Question

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Expert Solution & Answer

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Answer 3

Question

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Expert Solution & Answer

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Answer 4

Question

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Expert Solution & Answer

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Answer 5

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Answer 6

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Answer 7

Chapter 20, Problem 29E

Interpretation Introduction

Interpretation:

The approximate half-life for the first order reaction is to be determined.

Set I Set II Set III

Time, s [A], M Time, s [A], M Time, s [A], M

0 1.00 0 1.00 0 1.00

25 0.78 25 0.75 25 0.80

50 0.61 50 0.50 50 0.67

75 0.47 75 0.25 75 0.57

100 0.37 100 0.00 100 0.50

150 0.22 150 0.40

200 0.14 200 0.33

250 0.08 250 0.29

Concept introduction:

Zero-order reaction- for this, rate of reaction is independent of the concentration.

And the graph of zero order reaction is-

The first order reaction is the one in which the rate is directly proportional to the concentration of one of the reactant.

And half-life is

Integral rate law for first order reaction is −

and

The second order reaction is the one in which the rate is directly proportional to the square of the concentration of one of the reactant.

Integral rate law for second order reaction is −

And the graph of second order reaction is-

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 20 - In the reaction 2A+BC+3D , reactant A is found to...Ch. 20 - From Figure 20-2 estimate the rate of reaction at...Ch. 20 - In the reaction A products, [A] is found to be...Ch. 20 - In the reaction A products, at t = 0. [A]= 0.1565...Ch. 20 - In the reaction A products. 4.40 min after the...Ch. 20 - Refer to Experiment 2 of Table 20.3 and to...Ch. 20 - For the reaction A+2BC ,the rate of reaction is...Ch. 20 - If the rate of reaction (20.3) is 5.7104 M s-1 ,...Ch. 20 - In the reaction A(g)B(g)+C(g) , the totalpressure...Ch. 20 - At 65C , the half-life for the first-order...

Solution Summary: The author explains that the approximate half-life for the first order reaction is to be determined.

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Chapter 20 Solutions

Set I		Set II		Set III
Time, s	[A], M	Time, s	[A], M	Time, s	[A], M
0	1.00	0	1.00	0	1.00
25	0.78	25	0.75	25	0.80
50	0.61	50	0.50	50	0.67
75	0.47	75	0.25	75	0.57
100	0.37	100	0.00	100	0.50
150	0.22			150	0.40
200	0.14			200	0.33
250	0.08			250	0.29