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(a)
Interpretation:
The amide which forms the given amine on the treatment with
Concept introduction:
Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in
(b)
Interpretation:
The amide which forms the given amine on the treatment with
Concept introduction:
Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of amides to amines.
(c)
Interpretation:
The amide which forms the given amine on the treatment with
Concept introduction:
Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of amides to amines.
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Chapter 20 Solutions
Organic Chemistry-Package(Custom)
- Draw the structures for the carbonyl compound and amine required to synthesize benzyl methylamine via reductive amination. Lone pairs do not need to be included.arrow_forwardPredict the major products formed when the following amines undergo exhaustivemethylation, treatment with Ag2O, and heating.N-ethylpiperidinearrow_forwardPredict the major products formed when the following amines undergo exhaustivemethylation, treatment with Ag2O, and heating.2-methylpiperidinearrow_forward
- 3. Which of the following amines will not undergo an acyl substitution reaction with methyl acetate (CH3CO2CH3)? A) NH3 B) H₂N C) H₂N D) H3C-N-CH3 CH3 E) All of these will react with methyl acetatearrow_forwardWhat are the products of the following hydrolysis? a primary amine and an aldehyde O a primary amine and a ketone O a secondary amine and a ketone O a secondary amine and an alkene O a primary amine and an alkene O a secondary amine and an aldehydearrow_forwardWhat products are formed when all of the amide and ester bonds arehydrolyzed in each of the following compounds? Tamiflu [part (a)] is the trade name of the antiviral agent oseltamivir, thought to be the most effective agent in treating influenza. Aspartame [part (b)] is the artificial sweetener used in Equal and many diet beverages. One of the products of this hydrolysis reaction is the amino acid phenylalanine. Infants afflicted with phenylketonuria cannot metabolize this amino acid, so it accumulates, causing mental retardation. When the affliction is identified early, a diet limiting the consumption of phenylalanine (and compounds like aspartame that are converted to it) can make a normal life possible.arrow_forward
- Which of the following reductive amination reactions will yield a secondary amine?arrow_forwardName the following amide. N- N butyl N methyl butanamide N,N diethyl butanamide N ethyl N methyl butanamide O N,N dimethyl butanamidearrow_forwardShow how to synthesize the following amines from the indicated starting materials below. Each of the final products may require several sequential steps. Draw the structure for each of the steps and show the reagents required. Starting material Final product h) 4-ethyl-3-methylhexan-1-ol 4-ethyl-3-methylhexan-1-amine i) 2-phenylacetyl chloride N-N-dimethyl-2-phenylethan-1-amine j) ethyl acetate N-ethylpropan-2-aminearrow_forward
- Which of the following materials will most likely form an ester too if subjected to the same process as aspirin synthesis? A Benzoic Acid B Benzamide C Benzaldehyde D Benzenolarrow_forwardWhat steps would be used to synthesize an organic amine? Group of answer choices Ketone + oxidizing agent →carboxylic acid + ammonia →organic amine Alkene + acid → alcohol + ammonia →organic amine Ether + acid →ester + ammonia →organic amine Alkane + acid → alcohol + ammonia →organic amine Carboxylic acid + alcohol →ester + ammonia →organic amine Aldehyde + oxidizing agent →carboxylic acid + ammonia → organic aminearrow_forwardDraw the structures for the carbonyl compound and amine required to synthesize the required amine via reductive amination. Lone pairs do not need to be included.arrow_forward
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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