(a) Interpretation: The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated. Concept introduction: The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Question

Want to see the full answer?

Answer 1

Question

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Propose a synthesis of 1-butanamine from the following: (a) a chloroalkane of three carbons (b) a chloroalkane of four carbons

Select the stronger base from each pair of compounds. (a) H₂CNH₂ or EtzN (b) CI or NH2 NH2 (c) .Q or EtzN (d) or (e) N or (f) H or H

4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

Answer 2

Question

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Answer 6

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Answer 7

Chapter 20, Problem 20.11P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol using microscopic reversibility is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms. Also in microscopic reversibility, if the mechanism of forward direction is known then the mechanism for backward direction is just opposites to the forward and vice versa.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction condition that is used to bring acid-catalyzed hydrolysis of methyl benzoate to benzoic acid and methanol when the formation is reversible is to be stated.

Concept introduction:

The microscopic reversibility states that the mechanism followed by a reaction in forward direction under some condition will have the same backward mechanism under similar conditions. The similar conditions are in terms of thermodynamic parameters not in photochemical terms.

Hydrolysis is the reaction of a compound with water leading to the breakdown of the compound into two parts. Hydrolysis of esters can take place in both acidic and alkaline medium. The product of hydrolysis of the ester is alcohol and carboxylic acid.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 20 - Prob. 20.1P Ch. 20 - Prob. 20.2P Ch. 20 - Prob. 20.3P Ch. 20 - Prob. 20.4P Ch. 20 - Prob. 20.5P Ch. 20 - Prob. 20.6P Ch. 20 - Prob. 20.7P Ch. 20 - Prob. 20.8P Ch. 20 - Prob. 20.9P Ch. 20 - Prob. 20.10P

Solution Summary: The author explains the detailed mechanism for the acid-catalyzed hydrolysis of methyl benzoate and methanol using microscopic reversibility.

Want to see the full answer?

Chapter 20 Solutions