The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected. Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix. Names of branches that occur commonly as side chains are listed below:

Question

16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

Answer 1

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Answer 2

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 3

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 4

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 5

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 6

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 7

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 8

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 9

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 12

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 13

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 14

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 15

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 16

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 17

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 18

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 19

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 20

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 21

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 22

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 23

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 24

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Answer 35

Ch. 2.1 - Prob. 2.1E Ch. 2.1 - Prob. 2.2E Ch. 2.1 - Prob. 2.3E Ch. 2.1 - Prob. 2.5TIY Ch. 2.1 - Prob. 2.6E Ch. 2.1 - Prob. 2.7E Ch. 2.2 - Prob. 2.8E Ch. 2.3 - Prob. 2.9E Ch. 2.3 - Prob. 2.10E Ch. 2.3 - Prob. 2.11E

Solution Summary: The author recommends that the structures corresponding to 2-methyl-3-propylpentane be drawn and the incorrect IUPAC names be corrected.

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