Atom in the bromoethane that is most is likely to react with oxygen of OH − should be predicted. Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species. The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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Answer 1

Question

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

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Answer 2

Question

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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Answer 3

Question

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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Answer 4

Question

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

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Answer 5

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 6

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 7

Chapter 2, Problem 40P

(a)

Interpretation Introduction

Interpretation: Atom in the bromoethane that is most is likely to react with oxygen of OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 8

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 9

(b)

Interpretation Introduction

Interpretation: Atom in propanal that is most is likely to react with the nitrogen of ammonia should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 10

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 11

(c)

Interpretation Introduction

Interpretation: Atom in the methoxyethane that is most is likely to react with H+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 12

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 13

(d)

Interpretation Introduction

Interpretation: Atom in 3-hexanone that is most is likely to react with CH3− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 14

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 15

(e)

Interpretation Introduction

Interpretation: Atom in the acetonitrile that is most likely to react with CH3+ should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 16

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 17

(f)

Interpretation Introduction

Interpretation: Atom in the butane that is most is likely to react with OH− should be predicted.

Concept introduction: The fundamental electrostatics suggests that electrons have more affinity for electron deficient sites in an organic compound. or positive charge. The curved arrow is appropriate mechanism to depict electron movement that occurs from electron rich species to electron deficient species.

The nucleophile is species with unshared lone pair or negative charge that makes it seek out positive center with a reaction. Likewise, electrophile seeks for electron rich center as it is positively charged center of substrate.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 2.1 - Prob. 2.1E Ch. 2.1 - Prob. 2.2E Ch. 2.1 - Prob. 2.3E Ch. 2.1 - Prob. 2.5TIY Ch. 2.1 - Prob. 2.6E Ch. 2.1 - Prob. 2.7E Ch. 2.2 - Prob. 2.8E Ch. 2.3 - Prob. 2.9E Ch. 2.3 - Prob. 2.10E Ch. 2.3 - Prob. 2.11E

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Chapter 2 Solutions