ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 2, Problem 64P
Interpretation Introduction
Interpretation: The
Concept introduction:As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.
The IUPAC name begins with prefix to designate the number of
Names of branches that occur commonly as side chains are listed below:
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Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
This organic molecule is dissolved in an acidic aqueous solution:
OH
OH
A short time later sensitive infrared spectroscopy reveals the presence of a new C = O stretch absorption. That is, there must now be a new molecule present
with at least one C = O bond.
In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule.
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Curved arrows are used to
illustrate the flow of electrons.
Use the reaction conditions
provided and follow the curved
arrows to draw the product of
this carbocation rearrangement.
Include all lone pairs and
charges as appropriate.
H
1,2-alkyl shift
+
Chapter 2 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
Ch. 2.1 - Prob. 2.1ECh. 2.1 - Prob. 2.2ECh. 2.1 - Prob. 2.3ECh. 2.1 - Prob. 2.5TIYCh. 2.1 - Prob. 2.6ECh. 2.1 - Prob. 2.7ECh. 2.2 - Prob. 2.8ECh. 2.3 - Prob. 2.9ECh. 2.3 - Prob. 2.10ECh. 2.3 - Prob. 2.11E
Ch. 2.3 - Prob. 2.12ECh. 2.3 - Prob. 2.13ECh. 2.3 - Prob. 2.14ECh. 2.3 - Prob. 2.15ECh. 2.3 - Prob. 2.17TIYCh. 2.3 - Prob. 2.19TIYCh. 2.5 - Prob. 2.20ECh. 2.6 - Prob. 2.21ECh. 2.6 - Prob. 2.22ECh. 2.6 - Prob. 2.23ECh. 2.6 - Prob. 2.25TIYCh. 2.7 - Prob. 2.26ECh. 2.9 - Prob. 2.28TIYCh. 2 - Prob. 31PCh. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - Prob. 36PCh. 2 - Prob. 37PCh. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - Prob. 40PCh. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Prob. 48PCh. 2 - Prob. 49PCh. 2 - Prob. 50PCh. 2 - Prob. 51PCh. 2 - Prob. 52PCh. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - Prob. 56PCh. 2 - Prob. 57PCh. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - Prob. 62PCh. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - Prob. 66P
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