Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 2, Problem 2.48E
The ideal
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Chapter 2 Solutions
Physical Chemistry
Ch. 2 - Calculatethe work performed by a person whoexertsa...Ch. 2 - Explain inyour own words why work done by the...Ch. 2 - Calculate the work in joules when a piston moves...Ch. 2 - Calculatethe work on the system whena piston is...Ch. 2 - Calculatethe work in joules needed to expanda...Ch. 2 - Consider exercise 2.5. Would the workbe more or...Ch. 2 - Apistonhaving0.033 mol ofgas at 35.0Cexpands...Ch. 2 - A bottle of soda has a head space containing 25.0...Ch. 2 - Prob. 2.9ECh. 2 - Calculate the specific heat of a material if 288J...
Ch. 2 - There is 3930 J of energy added to a 79.8-g sample...Ch. 2 - If the heat capacity varies withtemperature,...Ch. 2 - Liquid hydrogen fluoride, liquid water,and liquid...Ch. 2 - A 5-mmdiameter hailstone has a terminal velocity...Ch. 2 - A7.50-gpiece of iron at 100.0C is dropped into...Ch. 2 - With reference to Joules apparatus inFigure2.6,...Ch. 2 - Prob. 2.17ECh. 2 - True or false: Althoughwork done bya free...Ch. 2 - What arethe differencesbetween an open, a closed,...Ch. 2 - The statement Energycan beneithercreatednor...Ch. 2 - Prob. 2.21ECh. 2 - What is the change in internal energy when a gas...Ch. 2 - Calculate the work for the isothermal, reversible...Ch. 2 - Calculate the work donewhen 1.000 mole of an ideal...Ch. 2 - Apistonhaving0.033 mol of gas at 35.0C expands...Ch. 2 - Prob. 2.26ECh. 2 - Indicate which state function is equal to heat, q,...Ch. 2 - The distance between downtown San Francisco and...Ch. 2 - Is temperature astate function?Defend your answer.Ch. 2 - A piston reversibly and adiabatically contracts...Ch. 2 - Calculate U when 1.00 mol of H2 goes from 1.00...Ch. 2 - Many compressed gases come in large,heavy metal...Ch. 2 - Under what conditions will U be exactly zero for a...Ch. 2 - Aballoon filled with 0.505 mole of gascontracts...Ch. 2 - A piston having 7.23 g of steam at 110 C increases...Ch. 2 - It takes 2260 J to vaporize a gram of liquid water...Ch. 2 - True or false: Any process for which H is negative...Ch. 2 - Prob. 2.38ECh. 2 - A refrigerator contains approximately 17cubic...Ch. 2 - In a constant-volume calorimeter, 35.0g of H2cools...Ch. 2 - A 2.50-mol sample of gas is compressed...Ch. 2 - A 244-g amount of coffee in an open plastic cup...Ch. 2 - Prob. 2.43ECh. 2 - Starting with equation 2.27 andthe original...Ch. 2 - Derive the fact that HpT is also zero for an ideal...Ch. 2 - Define isobaric,isochoric, isenthalpic,and...Ch. 2 - Starting from the cyclicrule involvingthe Joule-...Ch. 2 - The ideal gas law is theequation of state for an...Ch. 2 - Prob. 2.49ECh. 2 - Estimatethe final temperature of a mole of gas at...Ch. 2 - With regard to exercise 2.50, how accurate do you...Ch. 2 - Use the data in Table 2.2 to determine Hp T for Ar...Ch. 2 - Use the data in Table 2.2 to determine PH T for N2...Ch. 2 - Someone proposes thatthe Joule-Thomson coefficient...Ch. 2 - Why is equation2.37 written interms of CV and Cp...Ch. 2 - What are the numerical values of the heat...Ch. 2 - In a constant-pressure calorimeter that is, one...Ch. 2 - What is the finaltemperature of0.122 mole...Ch. 2 - Prob. 2.59ECh. 2 - Show that =5/3 for a monatomic ideal gas.Ch. 2 - Prob. 2.61ECh. 2 - Prob. 2.62ECh. 2 - A 1.00 mol sample of H2 is carefully warmed from...Ch. 2 - Asampleof a monatomic ideal gas doubles itsvolume...Ch. 2 - A sample of an ideal diatomic gas is compressed...Ch. 2 - In orbit about Earth, a weather balloonjettisons a...Ch. 2 - Prob. 2.67ECh. 2 - Prob. 2.68ECh. 2 - If pumping up an automobile tire is assumed to be...Ch. 2 - Prob. 2.70ECh. 2 - Take the volume change into account and calculate...Ch. 2 - How much work is performed by 1 mole of water...Ch. 2 - Why are steam burns so much worse than water burns...Ch. 2 - How many grams of water at 0C will be melted by...Ch. 2 - Draw a diagram like Figure 2.11 that illustrates...Ch. 2 - Determine the rxnH(25C) of the following reaction:...Ch. 2 - Determine rxnH 25 C for the following reaction: NO...Ch. 2 - The enthalpy of combustion of...Ch. 2 - The enthalpy of combustion of diamond is -395.4...Ch. 2 - Using Hesss law, writeout allof the formation...Ch. 2 - Sublimation is the phase change from solid to gas...Ch. 2 - The thermite reaction combines aluminum powder and...Ch. 2 - Benzoic acid, C6H5COOH, is a common standard used...Ch. 2 - Assume that 1.20 g of benzoicacid, C6H5COOH, is...Ch. 2 - Natural gas is mostly CH4. When it burns, the...Ch. 2 - Assuming constant heatcapacities for products and...Ch. 2 - Use the heat capacities of the products and...Ch. 2 - The following are values of heat capacity for...Ch. 2 - Prob. 2.89ECh. 2 - Prob. 2.90ECh. 2 - The Dieterici equation of state for one mole of...Ch. 2 - Prob. 2.92ECh. 2 - Find the enthalpies of the combustion reactions...
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- Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff: Ag₂ CO3 = 2 Ag+ caq) + co} (aq) ksp = 8.10 × 10-12 Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5 a) which salt will precipitate first? (b) What % of the first anion precipitated will remain in the solution. by the time the second anion starts to precipitate? (c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate explanation per answerarrow_forwardPart 4. Butanoic acid (ka= 1.52× 10-5) has a partition coefficient of 3.0 (favors benzene) when distributed bet. water and benzene. What is the formal concentration of butanoic acid in each phase when 0.10M aqueous butanoic acid is extracted w❘ 25 mL of benzene 100 mL of a) at pit 5.00 b) at pH 9.00arrow_forwardCalculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0 Group of answer choices 0.0269 kJ/mole 2610 kJ/mole 27.6 kJ/mole 0.215 kJ/mole 20.8 kJ/molearrow_forward
- Calculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0 choices: 0.0269 kJ/mole 2610 kJ/mole 27.6 kJ/mole 0.215 kJ/mole 20.8 kJ/molearrow_forwardCalculate activation energy (Ea) from the following kinetic data: Temp (oC) Time (s) 23.0 180. 32.1 131 40.0 101 51.8 86.0arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Rank the compounds in each group below according to their reactivity toward electrophilic aromatic substitution (most reactive = 1; least reactive = 3). Place the number corresponding to the compounds' relative reactivity in the blank below the compound. a. CH₂F CH3 F b. At what position, and on what ring, is bromination of phenyl benzoate expected to occur? Explain your answer. :0: C-O phenyl benzoate 6.Consider the reaction below to answer the following questions. A B C NO₂ FeBr3 + Br₂ D a. The nucleophile in the reaction is: BODADES b. The Lewis acid catalyst in the reaction is: C. This reaction proceeds d. Draw the structure of product D. (faster or slower) than benzene.arrow_forwardPart 2. A solution of 6.00g of substance B in 100.0mL of aqueous solution is in equilibrium, at room temperature, wl a solution of B in diethyl ether (ethoxyethane) containing 25.0 g of B in 50.0 mL 9) what is the distribution coefficient of substance B b) what is the mass of B extracted by shaking 200 ml of an aqueous solution containing 10g of B with call at room temp): i) 100 mL of diethyl ether ii) 50ml of diethyl ether twice iii) 25ml of diethyl ether four timesarrow_forward- Rank the following groups of compounds from most acidic (1) to least acidic (4). Place the number corresponding to the compound's relative rank in the blank below the structure. a. NO₂ NO₂ CH2CH2CH2CH2OH CH3 CH3CH2CHOH CH3CH2CH2CH2OH NO₂ CH3CHCH2CH2OH b. OH OH CH₂OH CO₂H HC CN CN CNarrow_forward
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