(a) Explanation The molecular electronic configuration of CF is, CF= ( σ1s ) 2 ( σ * 1s ) 2 ( σ2s ) 2 ( σ * 2s ) 2 ( σ2p ) 2 ( π2p x ) 2 = ( π2p y ) 2 ( π2p x ) 1 The bond order of CF is calculated as, Bond order= 10-5 2 Bond order= 2 .5 The bond order of CF is 2 (b) Interpretation Introduction Interpretation: The species that may be diamagnetic has to be predicted and the reason has to be explained.

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM

7th Edition

ISBN: 9781319399849

Author: ATKINS

Publisher: MAC HIGHER

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Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.

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Question

Chapter 2, Problem 2.33E

(a)

Interpretation Introduction

Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

(b)

Interpretation Introduction

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.

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Chapter 2, Problem 2.32E

Chapter 2, Problem 2.34E

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. Assume that the third-period element phosphorus forms a diatomic molecule, P2, in an analogous way as nitrogen does to form N2. (a) Write the electronic configuration for P2. Use [Ne2] to represent the electron configuration for the first two periods. (b) Calculate its bond order. (c) What are its magnetic properties (diamagnetic or paramagnetic)?

(a) Why do stable xenon fluorides have an even number of F atoms? (b) Why do the ionic species XeF₃⁺ and XeF₇⁻ have odd numbers of F atoms? (c) Predict the shape of XeF₃⁺ .

The sulfate ion can be represented with four S-O bonds or with two S-O and two So=O bonds.(a) Which representation is better from the standpoint of formal charges?(b) What is the shape of the sulfate ion, and what hybrid orbitals of S are postulated for the σ bonding?(c) In view of the answer to part (b), what orbitals of S must be used for the π bonds? What orbitals of O?(d) Draw a diagram to show how one atomic orbital from S and one from O overlap to form a π bond.

Chapter 2 Solutions

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 1TERM

Ch. 2 - Prob. 2A.1AST Ch. 2 - Prob. 2A.1BST Ch. 2 - Prob. 2A.2AST Ch. 2 - Prob. 2A.2BST Ch. 2 - Prob. 2A.3AST Ch. 2 - Prob. 2A.3BST Ch. 2 - Prob. 2A.4AST Ch. 2 - Prob. 2A.4BST Ch. 2 - Prob. 2A.1E Ch. 2 - Prob. 2A.2E

Ch. 2 - Prob. 2A.3E Ch. 2 - Prob. 2A.4E Ch. 2 - Prob. 2A.5E Ch. 2 - Prob. 2A.6E Ch. 2 - Prob. 2A.7E Ch. 2 - Prob. 2A.8E Ch. 2 - Prob. 2A.9E Ch. 2 - Prob. 2A.10E Ch. 2 - Prob. 2A.11E Ch. 2 - Prob. 2A.12E Ch. 2 - Prob. 2A.13E Ch. 2 - Prob. 2A.14E Ch. 2 - Prob. 2A.15E Ch. 2 - Prob. 2A.16E Ch. 2 - Prob. 2A.17E Ch. 2 - Prob. 2A.18E Ch. 2 - Prob. 2A.19E Ch. 2 - Prob. 2A.20E Ch. 2 - Prob. 2A.21E Ch. 2 - Prob. 2A.22E Ch. 2 - Prob. 2A.23E Ch. 2 - Prob. 2A.24E Ch. 2 - Prob. 2A.25E Ch. 2 - Prob. 2A.26E Ch. 2 - Prob. 2A.27E Ch. 2 - Prob. 2A.28E Ch. 2 - Prob. 2A.29E Ch. 2 - Prob. 2A.30E Ch. 2 - Prob. 2B.1AST Ch. 2 - Prob. 2B.1BST Ch. 2 - Prob. 2B.2AST Ch. 2 - Prob. 2B.2BST Ch. 2 - Prob. 2B.3AST Ch. 2 - Prob. 2B.3BST Ch. 2 - Prob. 2B.4AST Ch. 2 - Prob. 2B.4BST Ch. 2 - Prob. 2B.5AST Ch. 2 - Prob. 2B.5BST Ch. 2 - Prob. 2B.1E Ch. 2 - Prob. 2B.2E Ch. 2 - Prob. 2B.3E Ch. 2 - Prob. 2B.4E Ch. 2 - Prob. 2B.5E Ch. 2 - Prob. 2B.6E Ch. 2 - Prob. 2B.7E Ch. 2 - Prob. 2B.8E Ch. 2 - Prob. 2B.9E Ch. 2 - Prob. 2B.10E Ch. 2 - 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The molecules ( CF + ,CF,CF - ) have to arranged in the increasing C-F bond length.

Solution Summary: The author explains that the molecules C-F have to be arranged in the increasing bond length.

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Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.

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Chapter 2 Solutions

The molecules ( CF + ,CF,CF - ) have to arranged in the increasing C-F bond length.

Solution Summary: The author explains that the molecules C-F have to be arranged in the increasing bond length.

Concept explainers

Videos

Interpretation: The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation: The species that may be diamagnetic has to be predicted and the reason has to be explained.

Want to see the full answer?

Chapter 2 Solutions

Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.