The mechanism for the hydrolysis of the given iminium chloride in aqueous HCl has to be written. Concept introduction: Enamine: An enamine is a compound where the lone pair of electrons in the nitrogen atom of C − N bond gets delocalized by the presence of nearby C = C bond. Hydrolysis of enamine: Under acidic conditions, enamine reacts with water to give corresponding ketone and secondary amine . Here, the bond between nitrogen and the s p 2 carbon attached to it gets cleaved. Hydrolysis of iminium halides will produce an alkylated aldehyde or ketone.

Question

Which of the following sets of elements is not a Dobereiner triad? (Choose the best answer.) Group of answer choices Li-Na-K Al-Ga-In Cr-Mo-W K-Rb-Cs

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.5, Problem 19.8P

Interpretation Introduction

Interpretation:

The mechanism for the hydrolysis of the given iminium chloride in aqueous HCl has to be written.

Concept introduction:

Enamine:

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

Hydrolysis of enamine: Under acidic conditions, enamine reacts with water to give corresponding ketone and secondary amine.

Here, the bond between nitrogen and the sp2 carbon attached to it gets cleaved.

Hydrolysis of iminium halides will produce an alkylated aldehyde or ketone.

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Which of the following sets of elements is not a Dobereiner triad? (Choose the best answer.) Group of answer choices Li-Na-K Al-Ga-In Cr-Mo-W K-Rb-Cs

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.5, Problem 19.8P

Interpretation Introduction

Interpretation:

The mechanism for the hydrolysis of the given iminium chloride in aqueous HCl has to be written.

Concept introduction:

Enamine:

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

Hydrolysis of enamine: Under acidic conditions, enamine reacts with water to give corresponding ketone and secondary amine.

Here, the bond between nitrogen and the sp2 carbon attached to it gets cleaved.

Hydrolysis of iminium halides will produce an alkylated aldehyde or ketone.

Expert Solution & Answer

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Check out sample textbook solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.5, Problem 19.8P

Interpretation Introduction

Interpretation:

The mechanism for the hydrolysis of the given iminium chloride in aqueous HCl has to be written.

Concept introduction:

Enamine:

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

Hydrolysis of enamine: Under acidic conditions, enamine reacts with water to give corresponding ketone and secondary amine.

Here, the bond between nitrogen and the sp2 carbon attached to it gets cleaved.

Hydrolysis of iminium halides will produce an alkylated aldehyde or ketone.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.5, Problem 19.8P

Interpretation Introduction