The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene. Concept Introduction: Nomenclature of benzene and its derivative compounds: Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene. When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound. Nomenclature of benzene compound with more substituents, If one of the substituents imparts a special name, name the molecule as a derivative of that parent. If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”. Example: To indicate relative position on a benzene ring, three terms are mainly used and they are, (1) Ortho-(o): On adjacent carbons (1,2) (2) Meta-(m): Separated by one carbon (1,3) (3) Para-(p): Separated by two carbons (1,4)

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Answer 1

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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1 Please provide an efficient synthesis of the product below from the starting material. Use the starting material as the ONLY source of carbon atoms. Show the synthesis of each compound that would be used in the overall synthesis of the product. [This synthesis uses alkyne and alcohol chemistry.]

10- 4000 20 20 30- %Reflectance 60 50- 09 60- 40- Date: Thu Feb 06 17:30:02 2025 (GMT-05:0(UnknownP Scans: 8 Resolution: 2.000 70 70 88 80 3500 3000 2500 90 100 00 Wavenumbers (cm-1) 2000 1500 2983.10 2359.13 1602.52 1584.22 1451.19 1391.87 1367.07 1314.37 1174.34 1070.13 1027.33 1714.16 1269.47 1000 1106.08 1001.14 937.02 873.60 850.20 780.22 686.91 674.38 643.09 617.98 02/06/25 16:38:20

d. Draw arrow-pushing mechanism for an enzymatic retro-aldol reaction of the following hexose. Use B: and/or HA as needed. OH OH سية HO OH OH

Answer 2

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 3

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 4

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 5

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 6

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 7

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 8

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 9

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 10

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 11

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 12

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 13

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.1 - Draw the structure for each of the following: a....Ch. 19.2 - PROBLEM 2 If electrophilic addition to benzene is...Ch. 19.4 - Why does hydration inactivate FeBr3?Ch. 19.6 - Prob. 5P Ch. 19.7 - Prob. 6P Ch. 19.8 - What is the major product of a Friedel-Crafts...Ch. 19.10 - Describe two ways to prepare each of the following...Ch. 19.12 - Prob. 9P Ch. 19.13 - Name the following:Ch. 19.13 - Prob. 12P

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