The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified. Concept Introduction: A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal. The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal. The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

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Answer 1

Question

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

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424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)

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Answer 2

Question

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Expert Solution & Answer

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Answer 3

Question

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Expert Solution & Answer

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Answer 4

Question

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Expert Solution & Answer

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Answer 5

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Answer 6

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

Answer 7

Chapter 19.16, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The strongest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Concept Introduction:

A substituent attached to aromatic ring has two properties – inductive electron withdrawal and resonance electron withdrawal.

The substituent when attached to benzene ring withdraws electrons through the sigma bonds of benzene and it is called inductive electron withdrawal.

The substituent when attached to benzene ring donates electrons through the pi bonds of benzene and it is called resonance electron donation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 19.1 - Draw the structure for each of the following: a....Ch. 19.2 - PROBLEM 2 If electrophilic addition to benzene is...Ch. 19.4 - Why does hydration inactivate FeBr3?Ch. 19.6 - Prob. 5P Ch. 19.7 - Prob. 6P Ch. 19.8 - What is the major product of a Friedel-Crafts...Ch. 19.10 - Describe two ways to prepare each of the following...Ch. 19.12 - Prob. 9P Ch. 19.13 - Name the following:Ch. 19.13 - Prob. 12P

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The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

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Chapter 19 Solutions

Concept explainers

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Interpretation: The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.

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Chapter 19 Solutions

Interpretation:

The weakest acid among benzoic acid, o-fluorobenzoic acid and o-chlorobenzoic acid has to be identified.