PHYSICS F/SCI.+ENGRS.,STAND.-W/ACCESS
PHYSICS F/SCI.+ENGRS.,STAND.-W/ACCESS
6th Edition
ISBN: 9781429206099
Author: Tipler
Publisher: MAC HIGHER
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Chapter 19, Problem 55P
To determine

The proof that net entropy of universe increases.

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One of the statements of the second law is that “heat cannot flow from a colder body to awarmer one without external aid”. Assume two systems, 1 and 2, at T1 and T2 (whereT2 > T1 ). Show that if a quantity of heat q did flow spontaneously from 1 to 2, the processwould result in a decrease in the entropy of the universe. [You may assume that the heat flowsso slowly that the process can be regarded as reversible. Assume also that the loss of heat bythe system 1 and the gain of heat by 2 do not affect T1 and T2 .]
QUESTION 2: In a frictionless piston-cylinder assembly, it is initially submerged as a saturated liquid at a pressure of 200 kPa. Then, 450 kJ of heat transfer occurs from a source with a temperature of 500 0C to water and some of the water evaporates at constant pressure. Show whether this state change is feasible or not, considering the increase of entropy principle.
An ice cube (mass 30 g) at 0°C is left sitting on the kitchen table, where it gradually melts. The temperature in the kitchen is 25°C. (a)     Calculate the change in the entropy of the ice cube as it melts into water at 0°C. (Don't worry about the fact that the volume changes somewhat.) (b)     Calculate the change in the entropy of the water (from the melted ice) as its temperature rises from 0°C to 25°C. (c)     Calculate the change in the entropy of the kitchen as it gives up heat to the melting ice/water. (d)     Calculate the net change in the entropy of the universe during this process. Is the net change positive, negative, or zero? Is this what you would expect?

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PHYSICS F/SCI.+ENGRS.,STAND.-W/ACCESS

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