
Concept explainers
Interpretation: The process in which neutron to proton ratio decreases needs to be explained.
Concept introduction: The ratio of its number of the neutron to its number of protons is called n/p ratio of an atomic nucleus.
n/p ratio indicates the stability of the nucleus. A nuclide is most stable when n/p ratio is equal to 1 (when number of neutrons and number of protons are same). If n/p ratio is greater or lesser than 1 then radioactive nuclide decays by various radioactive decay process to approach a value which closer to one.
Number of neutron

Answer to Problem 53A
Only option “a” is correct.
Explanation of Solution
A beta decay reaction can be represented as:
Where
A obvious from the reaction that in beta emission proton number increases but number of neutron decreases and hence n/p ratio also decreases.
An alpha decay reaction can be represented as:
Heavier nucleus having higher number of neutrons decays by alpha emission.
X and Z are both reduced by 2. Since for nuclei that can decay by alpha emission there are always more neutrons in a nucleus than protons overall result is decrease of n/p value.
A positron decay reaction can be represented as:
Positron decay occurs in nuclide having low n/p ratio. Since one proton decreases in positron emission overall result is that n/p ratio increases.
An electron capture reaction can be represented as:
Here also n/p ratio increases.
In gamma decay neither mass not proton number changes and hence n/p ratio remains same.
Chapter 19 Solutions
World of Chemistry, 3rd edition
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