Introduction To General, Organic, And Biochemistry
Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 19, Problem 3P
Interpretation Introduction

Interpretation:

The difference in structure between an aldose and a ketose and between an aldopentose and a ketopentose should be determined.

Concept introduction:

Carbohydrates means hydrate of carbon, they have the general formula Cm(H2O)n (m and n can be same or different). For example: the formula of Glucose is C6 H12 O6, which can alternatively be written as C6 (H2 O)6.

At the molecular level, carbohydrates are polyhydroxy aldehydes and polyhydroxy ketones.

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3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1. For an unknown compound with a molecular formula of C8H100: a. What is the DU? (show your work) b. Solve the structure and assign each of the following spectra. 8 6 2 ō (ppm) 4 2 0 200 150 100 50 ō (ppm) LOD D 4000 3000 2000 1500 1000 500 HAVENUMBERI -11

Chapter 19 Solutions

Introduction To General, Organic, And Biochemistry

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