CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 19, Problem 19.67SP
How are standard reduction potentials defined?
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Chapter 19 Solutions
CHEMISTRY-TEXT
Ch. 19 - Balance the following net ionic equation by the...Ch. 19 - Balance the following net ionic equation by the...Ch. 19 - Prob. 19.3PCh. 19 - Balance the following net ionic equation by the...Ch. 19 - Prob. 19.5PCh. 19 - Prob. 19.6ACh. 19 - PRACTICE 18.7 Write a balanced equation for the...Ch. 19 - Consider the following galvanic cell with...Ch. 19 - The standard cell potential at 25oC is 1.20 V for...Ch. 19 - The standard free-energy change is 59.8kJ for the...
Ch. 19 - Which substance is the strongest reducting agent:...Ch. 19 - Consider the following table of standard reduction...Ch. 19 - Use Table 19.1 to calculate the value of Eo for...Ch. 19 - Prob. 19.14ACh. 19 - Prob. 19.15PCh. 19 - Prob. 19.16ACh. 19 - Consider a galvanic cell that uses the reaction...Ch. 19 - Accidentally chewing on a stray fragment of...Ch. 19 - Consider the following galvanic cell: What is the...Ch. 19 - Prob. 19.20ACh. 19 - What is the pH of the solution in the anode...Ch. 19 - Prob. 19.22ACh. 19 - Use the data in Table 19.1 to calculate the...Ch. 19 - Prob. 19.24ACh. 19 - Prob. 19.25PCh. 19 - Prob. 19.26ACh. 19 - In what ways are fuel cells and batteries similar,...Ch. 19 - Prob. 19.28PCh. 19 - The cell reaction in a hydrogen—oxygen fuel cell...Ch. 19 - Prob. 19.30PCh. 19 - Prob. 19.31PCh. 19 - A steam—hydrocarbon reforming process is one...Ch. 19 - Another method of hydrogen production is the...Ch. 19 - The following picture of a galvanic cell has lead...Ch. 19 - Prob. 19.35CPCh. 19 - Prob. 19.36CPCh. 19 - Prob. 19.37CPCh. 19 - Sketch a cell with inert electrodes suitable for...Ch. 19 - Prob. 19.39CPCh. 19 - Prob. 19.40CPCh. 19 - Consider the following galvanic cell with 0.10 M...Ch. 19 - Classify each of the following unbalanced...Ch. 19 - Classify each of the following unbalanced...Ch. 19 - Prob. 19.44SPCh. 19 - Prob. 19.45SPCh. 19 - Write unbalanced oxidation and reduction...Ch. 19 - Prob. 19.47SPCh. 19 - Balance the following half-reactions. (acidic)...Ch. 19 - Prob. 19.49SPCh. 19 - Write balanced net ionic equations for the...Ch. 19 - Write balanced net ionic equations for the...Ch. 19 - Write balanced net ionic equations for the...Ch. 19 - Prob. 19.53SPCh. 19 - Why is the cathode of a galvanic cell considered...Ch. 19 - What is the function of a salt bridge in a...Ch. 19 - Describe galvanic cells that use the following...Ch. 19 - Prob. 19.57SPCh. 19 - Write a balanced equation for the overall cell...Ch. 19 - Write the shorthand notation for a galvanic cell...Ch. 19 - Write the standard shorthand notation for a...Ch. 19 - Write the standard shorthand notation for a...Ch. 19 - An H2/H+ half-cell (anode) and an Ag+/Ag half-cell...Ch. 19 - A galvanic cell is constructed from a Zn/Zn2+...Ch. 19 - Write balanced equations for the electrode and...Ch. 19 - Prob. 19.65SPCh. 19 - What conditions must be met for a cell potential E...Ch. 19 - How are standard reduction potentials defined?Ch. 19 - The silver oxide-zinc battery used in watches...Ch. 19 - The standard cell potential for a lead storage...Ch. 19 - What is the value of x for the following reaction...Ch. 19 - Prob. 19.71SPCh. 19 - Use the standard free energies of formation in...Ch. 19 - Prob. 19.73SPCh. 19 - Arrange the following oxidizing agents in order of...Ch. 19 - Prob. 19.75SPCh. 19 - Consider the following substances:...Ch. 19 - Prob. 19.77SPCh. 19 - Consider the following substances:...Ch. 19 - Prob. 19.79SPCh. 19 - Use the data in Appendix D to predict whether the...Ch. 19 - Prob. 19.81SPCh. 19 - Prob. 19.82SPCh. 19 - What reaction can occur, if any, when the...Ch. 19 - The standard potential for the following galvanic...Ch. 19 - The following reaction has an Eo value of 0.27 V:...Ch. 19 - Prob. 19.86SPCh. 19 - Prob. 19.87SPCh. 19 - Prob. 19.88SPCh. 19 - Calculate Eo and Go (in kilojoules) for the...Ch. 19 - Calculate Eo for each of the following reactions,...Ch. 19 - Calculate Eo for each of the following reactions,...Ch. 19 - Consider a galvanic cell that uses the following...Ch. 19 - Given the following half-reactions and Eo values,...Ch. 19 - Consider a galvanic cell that uses the reaction...Ch. 19 - Consider a galvanic cell based on the reaction...Ch. 19 - Prob. 19.96SPCh. 19 - Prob. 19.97SPCh. 19 - What is the Zn2+:Cu2+ concentration ratio in the...Ch. 19 - What is the Fe2+:Sn2+ concentration ratio in the...Ch. 19 - The Nernst equation applies to both cell reactions...Ch. 19 - When suspected drunk drivers are tested with a...Ch. 19 - What is the reduction potential at 25o C for the...Ch. 19 - At one time on Earth, iron was present mostly as...Ch. 19 - Standard reduction potentials for the Pb2+/Pb and...Ch. 19 - Prob. 19.105SPCh. 19 - Prob. 19.106SPCh. 19 - Prob. 19.107SPCh. 19 - Prob. 19.108SPCh. 19 - Prob. 19.109SPCh. 19 - Use the data in Table 19.1 to calculate the...Ch. 19 - From standard reduction potentials, calculate the...Ch. 19 - Calculate the equilibrium constant at 25 oC for...Ch. 19 - Calculate the equilibrium constant at 25 oC for...Ch. 19 - Prob. 19.114SPCh. 19 - Prob. 19.115SPCh. 19 - Prob. 19.116SPCh. 19 - Prob. 19.117SPCh. 19 - Write a balanced equation for the overall cell...Ch. 19 - Prob. 19.119SPCh. 19 - You are on your dream vacation at the beach when a...Ch. 19 - A storm has knocked out power to your beach house,...Ch. 19 - For a lead storage battery: (a) Sketch one cell...Ch. 19 - A mercury battery uses the following electrode...Ch. 19 - Prob. 19.124SPCh. 19 - Prob. 19.125SPCh. 19 - Prob. 19.126SPCh. 19 - Prob. 19.127SPCh. 19 - Prob. 19.128SPCh. 19 - Prob. 19.129SPCh. 19 - Prob. 19.130SPCh. 19 - If the metal zinc were not available for the...Ch. 19 - Prob. 19.132SPCh. 19 - Prob. 19.133SPCh. 19 - Prob. 19.134SPCh. 19 - Prob. 19.135SPCh. 19 - Prob. 19.136SPCh. 19 - Predict the anode, cathode, and overall cell...Ch. 19 - Prob. 19.138SPCh. 19 - Prob. 19.139SPCh. 19 - Prob. 19.140SPCh. 19 - Prob. 19.141SPCh. 19 - Prob. 19.142SPCh. 19 - What is the metal ion in a metal nitrate solution...Ch. 19 - Prob. 19.144SPCh. 19 - Prob. 19.145SPCh. 19 - Prob. 19.146SPCh. 19 - Prob. 19.147SPCh. 19 - Consider the following half-reactions and Eo...Ch. 19 - Consider a galvanic cell that uses the following...Ch. 19 - Prob. 19.150MPCh. 19 - Prob. 19.151MPCh. 19 - Prob. 19.152MPCh. 19 - Prob. 19.153MPCh. 19 - Prob. 19.154MPCh. 19 - The reaction of MnO4- with oxalic acid (H2C2O4) in...Ch. 19 - Calculate the standard reduction potential for...Ch. 19 - Prob. 19.157MPCh. 19 - Prob. 19.158MPCh. 19 - Consider a galvanic cell that utilizes the...Ch. 19 - Prob. 19.160MPCh. 19 - Prob. 19.161MPCh. 19 - Prob. 19.162MPCh. 19 - Prob. 19.163MPCh. 19 - Consider the redox titration of 100.0 mL of a...
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- Given the following two standard reduction potentials, solve for the standard reduction potential of the half-reaction M3++eM2+ (Hint: You must use the extensive property G to determine the standard reduction potential.)arrow_forwardA standard galvanic cell is constructed so that the overall cell reaction is 2A13++(aq)+3M(s)3M2+(aq)+2A1(s) Where M is an unknown metal. If G = 411 kJ for the overall cell reaction, identify the metal used to construct the standard cell.arrow_forwardUse the data from the table of standard reduction potentials in Appendix H to calculate the standard potential of the cell based on each of the following reactions. In each case, state whether the reaction proceeds spontaneously as written or spontaneously in the reverse direction under standard-state conditions. (a) H2(g)+Cl2(g)2H+(aq)+2Cl(aq) (b) Al3+(aq)+3Cr2+(aq)Al(s)+3Cr3+(aq) (c) Fe2+(aq)+Ag+(aq)Fe3+(aq)+Ag(s)arrow_forward
- The mass of three different metal electrodes, each from a different galvanic cell, were determined before and after the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes. The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, given the label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass. Make an educated guess as to which electrodes were active and which were inert electrodes, and which were anode(s) and which were the cathode(s).arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardGiven this reaction, its standard potential, and the standard half-cell potential of 0.34 V for the Cu2+ |Cu half-cell, calculate E° for the Fe(s)|Fe2+(aq) half-cell.arrow_forward
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- For each reaction listed, determine its standard cell potential at 25 C and whether the reaction is spontaneous at standard conditions. (a) Mn(s)+Ni2+(aq)Mn2+(aq)+Ni(s) (b) 3Cu2+(aq)+2Al(s)2Al3+(aq)+3Cu(s) (c) Na(s)+LiNO3(aq)NaNO3(aq)+Li(s) (d) Ca(NO3)2(aq)+Ba(s)Ba(NO3)2(aq)+Ca(s)arrow_forwardConsider a galvanic cell based on the following half-reactions: a. What is the standard potential for this cell? b. A nonstandard cell is set up at 25C with [Mg2+] = 1.00 105 M. The cell potential is observed to be 4.01 V. Calculate [Au3+] in this cell.arrow_forwardIt took 150. s for a current of 1.25 A to plate out 0.109 g of a metal from a solution containing its cations. Show that it is not possible for the cations to have a charge of 1+.arrow_forward
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