Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 19, Problem 19.64E
Interpretation Introduction

Interpretation:

The reason as to why the diffusion stops when a solute gas is evenly spread in a system of solvent gas is to be stated.

Concept introduction:

Fick’s first law of diffusion gives the relation between diffusion and the concentration gradient in x direction. The expression for Fick’s first law of diffusion is,

dN1dt=DAdc1dx

Where,

dN1dt gives the diffusion of gas particles.

D is the proportionality constant.

dc1dx is the concentration gradient in x direction.

The value of constant D does not depend on the identity of the gas.

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Given these values, find the initial mole fraction and initial mass % of the solute (NaCl) Solvent (water) weight: 329.8g Solute (NaCl) weight: 20.8 Solute (NaCl) Molar mass=58.44 moles of solute (NaCl) = .356
Given these values, find the initial mole fraction and initial mass % of the solute (sucrose) Solvent (water) weight: 200g Solute (NaCl) weight: 232g Solute (NaCl) Molar mass=342.3 moles of solute (NaCl) = .678
Tendency of the solute to spread throughout the solution until the composition is homogeneous

Chapter 19 Solutions

Physical Chemistry

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