Basic Chemistry (5th Edition)
Basic Chemistry (5th Edition)
5th Edition
ISBN: 9780134138046
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 18.3, Problem 18.28QAP
Interpretation Introduction

Interpretation:

The balanced chemical equation for the hydrogenation process of glyceryl tripalmitoleate needs to be determined.

Concept Introduction:

Fatty acids are long chain carboxylic acid which may or may not have unsaturation in the molecule. They react with glycerol to form triglyceride. The reaction is called as esterification as carboxylic acid group react with alcoholic group to form ester group. Hydrogenation reaction leads to the saturation of fatty acid chain.

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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?  b. What is the purpose of the Na2SO4?  c. What equipment would you use to “concentrate [a solution] under reduced pressure”?

Chapter 18 Solutions

Basic Chemistry (5th Edition)

Ch. 18.1 - Prob. 18.11QAPCh. 18.1 - Prob. 18.12QAPCh. 18.2 - Prob. 18.13QAPCh. 18.2 - Prob. 18.14QAPCh. 18.2 - Prob. 18.15QAPCh. 18.2 - Prob. 18.16QAPCh. 18.2 - Prob. 18.17QAPCh. 18.2 - Prob. 18.18QAPCh. 18.2 - Prob. 18.19QAPCh. 18.2 - Prob. 18.20QAPCh. 18.3 - Prob. 18.21QAPCh. 18.3 - Prob. 18.22QAPCh. 18.3 - Caprylic acid is an 8-carbon saturated fatty acid...Ch. 18.3 - Prob. 18.24QAPCh. 18.3 - Prob. 18.25QAPCh. 18.3 - Why does olive oil have a lower melting point than...Ch. 18.3 - Prob. 18.27QAPCh. 18.3 - Prob. 18.28QAPCh. 18.3 - Write the balanced chemical equation for the NaOH...Ch. 18.3 - Prob. 18.30QAPCh. 18.3 - Prob. 18.31QAPCh. 18.3 - 18.32 What are the functional groups on the...Ch. 18.4 - Prob. 18.33QAPCh. 18.4 - Prob. 18.34QAPCh. 18.4 - Prob. 18.35QAPCh. 18.4 - Prob. 18.36QAPCh. 18.4 - Prob. 18.37QAPCh. 18.4 - Prob. 18.38QAPCh. 18.4 - Prob. 18.39QAPCh. 18.4 - Prob. 18.40QAPCh. 18.4 - Peptides isolated from rapeseed that may lower...Ch. 18.4 - Prob. 18.42QAPCh. 18.5 - Prob. 18.43QAPCh. 18.5 - Prob. 18.44QAPCh. 18.5 - Prob. 18.45QAPCh. 18.5 - Prob. 18.46QAPCh. 18.5 - Prob. 18.47QAPCh. 18.5 - Prob. 18.48QAPCh. 18.5 - Prob. 18.49QAPCh. 18.5 - Prob. 18.50QAPCh. 18.6 - Match the terms. (1) enzyme. (2) enzyme-substrate...Ch. 18.6 - 18.52 Match the terms. (1) active site, (2)...Ch. 18.6 - Prob. 18.53QAPCh. 18.6 - Prob. 18.54QAPCh. 18.7 - Prob. 18.55QAPCh. 18.7 - Prob. 18.56QAPCh. 18.7 - Prob. 18.57QAPCh. 18.7 - Prob. 18.58QAPCh. 18.7 - Prob. 18.59QAPCh. 18.7 - 18.60 Write the base sequence in a complementary...Ch. 18.7 - Prob. 18.61QAPCh. 18.7 - What is daughter DNA?Ch. 18.8 - Prob. 18.63QAPCh. 18.8 - Prob. 18.64QAPCh. 18.8 - What amino acid is coded for by each of the...Ch. 18.8 - Prob. 18.66QAPCh. 18.8 - Prob. 18.67QAPCh. 18.8 - Prob. 18.68QAPCh. 18 - Prob. 18.69FUCh. 18 - Prob. 18.70FUCh. 18 - Prob. 18.71UTCCh. 18 - Prob. 18.72UTCCh. 18 - Prob. 18.73UTCCh. 18 - Prob. 18.74UTCCh. 18 - Prob. 18.75UTCCh. 18 - Prob. 18.76UTCCh. 18 - Prob. 18.77UTCCh. 18 - Prob. 18.78UTCCh. 18 - Prob. 18.79UTCCh. 18 - Prob. 18.80UTCCh. 18 - Prob. 18.81UTCCh. 18 - Prob. 18.82UTCCh. 18 - Prob. 18.83AQAPCh. 18 - Prob. 18.84AQAPCh. 18 - Prob. 18.85AQAPCh. 18 - Prob. 18.86AQAPCh. 18 - Prob. 18.87AQAPCh. 18 - Prob. 18.88AQAPCh. 18 - Prob. 18.89AQAPCh. 18 - Draw the condensed structural formula for...Ch. 18 - Prob. 18.91AQAPCh. 18 - Prob. 18.92AQAPCh. 18 - Prob. 18.93AQAPCh. 18 - Prob. 18.94AQAPCh. 18 - Prob. 18.95AQAPCh. 18 - Prob. 18.96AQAPCh. 18 - Prob. 18.97CQCh. 18 - Prob. 18.98CQCh. 18 - Prob. 18.99CQCh. 18 - Prob. 18.100CQCh. 18 - Prob. 18.101CQCh. 18 - Prob. 18.102CQCh. 18 - Prob. 18.103CQCh. 18 - Prob. 18.104CQCh. 18 - Prob. 18.105CQCh. 18 - Prob. 18.106CQCh. 18 - Prob. 18.107CQCh. 18 - Prob. 18.108CQCh. 18 - Prob. 41CICh. 18 - Prob. 42CICh. 18 - Prob. 43CICh. 18 - Prob. 44CICh. 18 - Prob. 45CICh. 18 - Thalassemia is an inherited genetic mutation that...
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