(a) Interpretation: The structure corresponding to N-methylaniline is to be drawn. Concept Introduction: Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as- Primary amines ( RNH 2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group. Secondary amines ( R 2 NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups. Tertiary amine ( R 3 N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 1

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 3

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 4

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 5

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 6

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 7

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.1 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.2 - Prob. 18.6P Ch. 18.2 - Prob. 18.7P Ch. 18.3 - Prob. 18.8P Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.10P

Solution Summary: The author explains the structure corresponding to N-methylaniline and m-Ethylaniline.

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Chapter 18 Solutions