(a) Interpretation: The ammonium salt which is formed when the given amine is treated with HCl should be determined. Concept Introduction: Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

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Answer 1

Question

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

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Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0

Answer 2

Question

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

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Answer 3

Question

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

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Answer 4

Question

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

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Answer 5

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 6

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 7

Chapter 18, Problem 52P

Interpretation Introduction

(a)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The ammonium salt which is formed when the given amine is treated with HCl should be determined.

Concept Introduction:

Since amines have a lone pair of electrons on its N atom, they act as proton acceptors. When amines react with an acid, amine accepts protons from acid and forms its conjugate acid. Amines are basic than other organic compounds but are weaker bases than inorganic bases.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

Solution Summary: The author explains that amines have a lone pair of electrons on their N atom and act as proton acceptors.

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Chapter 18 Solutions