(a) Interpretation: The product formed when the amine, C H 3 C H 2 N H 2 is treated with H C l is to be explained. Concept Introduction: Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as- Primary amines ( RNH 2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group. Secondary amines ( R 2 NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups. Tertiary amine ( R 3 N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 1

Question

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H

H H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.

Answer 2

Question

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 3

Question

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 4

Question

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 5

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 6

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 7

Chapter 18.6, Problem 18.4PP

Interpretation Introduction

(a)

Interpretation:

The product formed when the amine, CH3CH2NH2 is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed when the amine, (CH3CH2)2NH is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed when the amine, (CH3CH2)3N is treated with HCl is to be explained.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

Solution Summary: The author explains that amines are organic compounds that are derived from ammonia by replacing one or more hydrogen atoms by the alkyl or aryl groups.

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