(a) Interpretation: The functional groups of methylphenidate needs to be identified. Concept introduction: The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Question

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Answer 1

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Answer 2

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 3

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 4

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 5

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 6

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Answer 7

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Answer 13

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

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Chapter 18 Solutions

Concept explainers

(d) Interpretation: The 2-phenylethylamine needs to be located in methylphenidate molecule. Concept introduction: The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

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Chapter 18 Solutions