Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 18, Problem 3Q
Interpretation Introduction

Interpretation:

The alkyl halide used in malonic ester synthesis of 4-methylpentanoic acid is to be identified.

Concept introduction:

The synthesis of mono di-substituted acetic acid, which is the useful counterpart of acetoacetic ester synthesis, is called malonic ester synthesis.

In malonic ester synthesis, the starting material is malonic ester and the most commonly used malonic ester is diethyl malonate.

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1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)

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Organic Chemistry

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