(a) Interpretation: The curved-arrow mechanisms for the given reaction is to be drawn. Concept introduction: The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

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Answer 1

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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So the thing is im trying to memorize VESPR Shapes in order to be able to solve problems like so, and I need help with making circles like the second image that's in blue or using an x and y axis plane in order to memorize these and be able to solve those type of problems. Especially like the ones given in the top / first image. (180 , 120 , 109.5) Can you help me with this.

Don't used hand raiting and don't used Ai solution

2. (15 points) Draw an appropriate mechanism for the following reaction. H N. H* + H₂O

Answer 2

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 3

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 4

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 5

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 6

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Answer 7

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author illustrates the curved-arrow mechanisms for the given reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group of the aromatic ring.

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Chapter 18 Solutions