The combustion of acetylene, C 2 H 2 , is a spontaneous reaction given by the equation 2 C 2 H 2 ( g ) + 5 O 2 ( g ) → 4 CO 2 ( g ) + 2 H 2 O ( l ) As expected for a combustion, the reaction is exothermic. What is the sign of Δ H °? What do you expect for the sign of Δ S° ? Explain the spontaneity of the reaction in terms of the enthalpy and entropy changes.
The combustion of acetylene, C 2 H 2 , is a spontaneous reaction given by the equation 2 C 2 H 2 ( g ) + 5 O 2 ( g ) → 4 CO 2 ( g ) + 2 H 2 O ( l ) As expected for a combustion, the reaction is exothermic. What is the sign of Δ H °? What do you expect for the sign of Δ S° ? Explain the spontaneity of the reaction in terms of the enthalpy and entropy changes.
Solution Summary: The author explains that the sign of entropy change and spontaneity of the given reaction has to be determined.
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
The combustion of acetylene, C2H2, is a spontaneous reaction given by the equation
2
C
2
H
2
(
g
)
+
5
O
2
(
g
)
→
4
CO
2
(
g
)
+
2
H
2
O
(
l
)
As expected for a combustion, the reaction is exothermic. What is the sign of ΔH°? What do you expect for the sign of ΔS°? Explain the spontaneity of the reaction in terms of the enthalpy and entropy changes.
Fill in the blanks by selecting the appropriate term from below:
For a process that is non-spontaneous and that favors products at equilibrium, we know that a) ΔrG∘ΔrG∘ _________, b) ΔunivSΔunivS _________, c) ΔsysSΔsysS _________, and d) ΔrH∘ΔrH∘ _________.
Highest occupied molecular orbital
Lowest unoccupied molecular orbital
Label all nodes and regions of highest and lowest electron density for both orbitals.
Relative Intensity
Part VI. consider the multi-step reaction below for compounds A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
20
NaоH
0103
Br
(B)
H2504
→ (c)
(A)
100-
MS-NU-0547
80
40
20
31
10
20
100-
MS2016-05353CM
80
60
100
MS-NJ-09-3
80
60
40
20
45
J.L
80
S1
84
M+
absent
राग
135 137
S2
62
164 166
11
S3
25
50
75
100
125
150
175
m/z
Chapter 18 Solutions
General Chemistry - Standalone book (MindTap Course List)
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY