(a)
Interpretation:
Whether the statement.
The general name of an aliphatic
Concept Introduction:
Alkanoic acid is the IUPAC name of carboxylic acid.
- First choose the longest continuous chain of carbon atoms having carboxyl group known as parent chain.
- The numbering of parent chain should be done in a way that the carboxyl group and substituents get the lowest number.
- The root name of the carbon chain is “oic” acid.
- The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
- The alkyl groups are written in alphabetical order.
(b)
Interpretation:
Whether the statement.
A molecule containing two COOH groups is called a dicarboxylic acid is true or false.
Concept Introduction:
Carboxylic acids containing two COOH groups are known as dicarboxylic acid.
(c)
Interpretation:
Whether the statement.
Ethanedioic (oxalic acid) acid is the simplest dicarboxylic acid is true or false.
Concept Introduction:
Oxalic acid contains total two carbon atoms. It’s IUPAC name is ethanedioic acid, here dioic represents the two carboxyl groups.
(d)
Interpretation:
Whether the statement.
3-Methylbutanoic acid is chiral is true or false.
Concept Introduction:
Chiral molecules are those in which there are four different groups attached tetrahedrally.
(e)
Interpretation:
Whether the statement.
The simplest carboxylic acid is methanoic acid (common name: formic acid), HCOOH is true or false.
Concept Introduction:
Formic acid is a carboxylic acid with one carbon.
(f)
Interpretation:
Whether the statement.
Benzoic acid is an
Concept Introduction:
Aromatic carboxylic acid must follow
(g)
Interpretation:
Whether the statement.
Formic acid, which is the common name for HCO2 H, is derived from the word Formica, which is the Latin name for ants is true or false.
Concept Introduction:
Formic acid is a carboxylic acid with one carbon.
(h)
Interpretation:
Whether the statement.
(S)-Lactic acid, CH3 -CHOH-COOH, contains two functional groups: a 20 alcohol and a carboxyl group are true or false.
Concept Introduction:
Lactic acid is 2-hydroxypropanoic acid.
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Chapter 18 Solutions
Introduction to General, Organic and Biochemistry
- 17-74 Glucose, C6H12O6, contains an aldehyde group but exists predominantly in the form of the cyclic hemiacetal shown here. We will discuss this cyclic form of glucose in Chapter 20. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. (a) Which carbon in glucose provides the —OH group and which provides the —CHO group? (b) Draw the alternative chair confirmations of D-glucose and state which of the two is the more stable.arrow_forwardWhat is the major organic product of the following reaction? (a) (b) NaBH4 CH3CH₂OH ? (c) (d) OHarrow_forwardWrite structures and describe thephysical properties of carboxylic acidsarrow_forward
- Draw the organic product formed when the followingcompounds undergo a substitution reaction: (a) acetic acid and1-hexanol; (b) propanoic acid and dimethylamine; (c) ethanoicacid and diethylamine.arrow_forwardIn each of the following reactions, two possible organic products can be formed. Draw both organic products in each case and then circle the one formed in greatest quantity in each case. HC (a) 1) NaH, 2) acid (b) CH,CH,OH (c) CH,CH,OH NH2 (d) Oarrow_forwardWhich of the following molecules (1) (2) CH,0-ČCH,CH, CH,CH,CH (3) О—С—Он (4) OH CH,CHCH,CH, (5) CH,-NH would: neutralize NaOH neutralize HCI yields an alcohol and an organic acid when hydrolyzed is easily oxidized to an acid would be classifed as aromatic could be oxidized to give a ketonearrow_forward
- Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forwardName the type of reaction; then predict the products. Make sure the reaction is balanced.arrow_forwardWrite the chemical equation for a pentanoate ion acting as base when it reacts with hydrochloric acid (HCI). Which is formula of this rule of reaction?arrow_forward
- Write an equation for the formation of the following compounds from the appropriate alcoholarrow_forward[10] 10] Q1. Do the following conversions as directed. Write the complete reaction equation. (a) Benzaldehyde to Benzoic Acid. (b) Propanal to 1-propanal (c) Cyclohexanone to Cyclohexanol (d) Acetaldehyde to Ethyl alcohol (e) Acetone to Iso-propyl alcoholarrow_forwardUsing the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forward
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