The complete, detailed mechanism for the given reaction is to be drawn. Concept introduction: The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

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Answer 1

Question

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

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Answer 2

Question

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

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Answer 3

Question

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

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Answer 4

Question

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

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Answer 5

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

Answer 6

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

Answer 7

Chapter 18, Problem 18.52P

Interpretation Introduction

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn.

Concept introduction:

The triple bond of the nitrile has polar π bonds. Due to the electronegativity difference between carbon and nitrogen, this bond is polarized, which results in the partial positive charge on carbon and partial negative charge on nitrogen. Secondary amines act as bases as well as nucleophiles. Since nitrogen is less electronegative than oxygen, it is more nucleophilic than oxygen.

Answer 8

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Answer 11

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

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Chapter 18 Solutions