Draw a Newman projection from carbon 3 to carbon 2 in the highest energy conformation for the following molecule. What is this conformation called? What kind of strain is present? Br
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- Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.Following is a chair conformation of cyclohexane with the carbon atoms numbered 1 through 6. (a) Draw hydrogen atoms that are above the plane of the ring on carbons 1 and 2 and below the plane of the ring on carbon 4. (b) Which of these hydrogens are equatorial? Which are axial? (c) Draw the alternative chair conformation. Which hydrogens are equatorial? Which are axial? Which are above the plane of the ring? Which are below it?
- Draw a Newman projection showing the lowest P.E. conformation of the following moleculesighting down the C2C3 bond (as indicated below). Show methyl and ethyl groups as Me and Et.Following is a planar hexagon representation for one isomer of 1,2,4-trimethylcyclohexane. Draw the alternative chair conformations of this compound and state which of the two is more stable.Font Paragraph Using a Newman projection, draw the most stable conformation of CH2-CH2. | ОН ОН
- Draw all the conformers of the molecule on the right as Newman projections sighted along the C3– C4 bond. Label the interactions present in each conformer. Rank the conformers from lowest to highest energy (some may be equal).Draw a Newman projection of 1-bromo-1-chloropropane in any staggered conformation. Draw the Newman projection as if you were looking down the C2-C1 bond, with C2 in the front.Draw a chair conformation of this molecule with (a) all CH3 groups in axial positions and (b) all CH3 groups in equatorial positions.
- position. Calculate the energy associated with steric strain in the following conformation. CH3 ОН Table of A-Values in kcal/mol -CH3 1.7 -ОН 0.87 -CH2CH3 1.75 -OCH3 0.67 -CH(CH3)2 2.15 -C(CH3)3 -CI 0.48 4.9 -Br 0.43Me2N and Me are attached to the carbon chain in molecule twoDraw the Newman projection of the anti and syn conformers for the following molecule by rotating the C-2 and C-3 bond.