The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified. Concept introduction: Oxidation state: As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

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Answer 1

Question

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

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Answer 3

Question

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

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Answer 4

Question

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

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Answer 5

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

Answer 6

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

Answer 7

Chapter 18, Problem 18.21CP

a)

Interpretation Introduction

Interpretation:

The oxidation state of oxygen in each oxide and the oxidation state of the other element has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

Answer 8

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

Answer 9

b)

Interpretation Introduction

Interpretation:

The bonding nature of metal oxides has to be identified.

Concept introduction:

Covalent bond:

The bond which involves sharing of electrons between the atoms present in the molecule

Ionic bond:

The bond which involves transfer of electrons between the atoms present in the molecule

Answer 10

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

Answer 11

c)

Interpretation Introduction

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

Answer 12

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

Answer 13

d)

Interpretation Introduction

Interpretation:

The identity of the metal in the compounds (1) and (2) has to be identified.

Concept introduction:

Oxidation state:

As per the IUPAC definition, the charge of the atom is the oxidation state of an atom after ionic approximation of its heteronuclear bonds or it is a number assigned to an atom or an element which represents the number of electrons lost or gained.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.2 - Prob. 18.3P Ch. 18.3 - Write the chemical formula of a compound that...Ch. 18.4 - Prob. 18.5P Ch. 18.4 - Prob. 18.6CP Ch. 18.4 - Prob. 18.7P Ch. 18.8 - Prob. 18.8CP Ch. 18.8 - Prob. 18.9P Ch. 18.9 - Prob. 18.10P

Solution Summary: The author explains the oxidation state of oxygen in each atom and the other element has to be identified.

Concept explainers

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons

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Chapter 18 Solutions

Solution Summary: The author explains the oxidation state of oxygen in each atom and the other element has to be identified.

Concept explainers

Interpretation: The bonding nature of metal oxides has to be identified. Concept introduction: Covalent bond: The bond which involves sharing of electrons between the atoms present in the molecule Ionic bond: The bond which involves transfer of electrons between the atoms present in the molecule

Interpretation: The acidic or basic nature of the oxides has to be identified. Concept introduction: Acid: The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond Base: The substance which is capable of donating a pair of nonbonding electrons

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Chapter 18 Solutions

Interpretation:

The acidic or basic nature of the oxides has to be identified.

Concept introduction:

Acid:

The substance which is capable of accepting a pair of nonbonding electrons and forms covalent bond

Base:

The substance which is capable of donating a pair of nonbonding electrons