Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written. Concept Introduction: Molecular orbital theory: Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below. Atomic orbital of equal energy combine together to form molecular orbital. Shape of molecular orbital depending on the shapes of combining atomic orbital. Bonding orbitals denoted by σ , π and δ and antibonding orbital are denoted by σ ∗ , π ∗ and δ ∗ . Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle. A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle. Paramagnetic and diamagnetic nature: If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

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Answer 1

Question

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

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Answer 2

Question

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Expert Solution & Answer

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Answer 3

Question

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Expert Solution & Answer

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Answer 4

Question

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Expert Solution & Answer

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Answer 5

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Answer 6

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

Answer 7

Chapter 18, Problem 18.20CP

(a)

Interpretation Introduction

Interpretation:

Given compound is whether the compound is peroxide or superoxide has to be identified and chemical formula of this compound should be written.

Concept Introduction:

Molecular orbital theory:

Molecular orbital theory states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital called molecular orbital. A brief outline of this theory is given below.

Atomic orbital of equal energy combine together to form molecular orbital.

Shape of molecular orbital depending on the shapes of combining atomic orbital.

Bonding orbitals denoted by σ, π and δ and antibonding orbital are denoted by σ∗, π∗ and δ∗.

Molecular orbital are filled in increasing order of their energies, starting with orbital of least energy. This is called Aufbau principle.

A molecular orbital is filled with only two electrons with opposite spins. This is called Paul’s exclusion principle.

Paramagnetic and diamagnetic nature:

If all electrons in the molecule are paired, the substance is diamagnetic nature and substance has unpaired electron(s) are called paramagnetic nature.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Whether the given compound is attracted or repelled by magnetic field has to be identified.

Concept Introduction:

Paramagnetic substance: If the substance has unpaired electron(s) which is paramagnetic in nature. Paramagnetic substance are attracted by magnetic fields due to having unpaired electron(s).

Diamagnetic substance: If all electrons in substance are paired which is diamagnetic in nature. Diamagnetic substance are repelled by magnetic fields due to having no unpaired electron.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.2 - Prob. 18.3P Ch. 18.3 - Write the chemical formula of a compound that...Ch. 18.4 - Prob. 18.5P Ch. 18.4 - Prob. 18.6CP Ch. 18.4 - Prob. 18.7P Ch. 18.8 - Prob. 18.8CP Ch. 18.8 - Prob. 18.9P Ch. 18.9 - Prob. 18.10P

Solution Summary: The author explains Molecular Orbital Theory, which states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital.

Videos

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Want to see the full answer?

Chapter 18 Solutions

Solution Summary: The author explains Molecular Orbital Theory, which states that atomic orbitals lose their individuality and electrons of the molecule present in the new orbital.

Videos

Interpretation: The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

Interpretation: The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.

Want to see the full answer?

Chapter 18 Solutions

Interpretation:

The molecular orbital derived from the atomic 2p orbital of Oxygen containing binary compound of Potassium is given. Oxygen-Oxygen bond energy and bond length in this compound with the corresponding properties of Oxygen molecule has to be compared.

Interpretation:

The given compound is treated with water, resulting aqueous solution is acidic or basic has to be explained.