A reaction taking place in an electrochemical cell and the equilibrium constant for the same reaction is given. The value of cell potential E for the same reaction is to be calculated. Concept introduction: The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation. The value of E cell is calculated using Nernst formula, E = E ° − ( R T n F ) ln ( Q ) At room temperature the above equation is specifies as, E = E ° − ( 0.0591 n ) log ( Q ) This relation is further used to determine the relation between Δ G ° and K , Δ G ° and E ° cell . To determine: The value of cell potential E for the given cell reaction.
A reaction taking place in an electrochemical cell and the equilibrium constant for the same reaction is given. The value of cell potential E for the same reaction is to be calculated. Concept introduction: The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation. The value of E cell is calculated using Nernst formula, E = E ° − ( R T n F ) ln ( Q ) At room temperature the above equation is specifies as, E = E ° − ( 0.0591 n ) log ( Q ) This relation is further used to determine the relation between Δ G ° and K , Δ G ° and E ° cell . To determine: The value of cell potential E for the given cell reaction.
Solution Summary: The author explains that the value of cell potential E for the given cell reaction is calculated using the Nernst equation.
Definition Definition Chemical reactions involving both oxidation and reduction processes. During a redox reaction, electron transfer takes place in such a way that one chemical compound gets reduced and the other gets oxidized.
Chapter 17, Problem 88E
Interpretation Introduction
Interpretation:
A reaction taking place in an electrochemical cell and the equilibrium constant for the same reaction is given. The value of cell potential
E for the same reaction is to be calculated.
Concept introduction:
The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.
The value of
Ecell is calculated using Nernst formula,
E=E°−(RTnF)ln(Q)
At room temperature the above equation is specifies as,
E=E°−(0.0591n)log(Q)
This relation is further used to determine the relation between
ΔG° and
K ,
ΔG° and
E°cell.
To determine: The value of cell potential
E for the given cell reaction.
81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
فا
Explanation
Check
Click and drag to start drawing a
structure.
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell