The reason behind the absence of + 1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time is to be stated. Concept introduction: The non-spontaneous reaction takes place in an electrolytic cell in which there occurs conversion of electrical energy into chemical energy and this is used for the electrolysis of a metal. The charge generated in the cell is calculated as, Q = I t When electricity is passed through an electrolytic cell, at that time the amount of the substance that is liberated at an electrode is given by, W = Z Q = Z I t The value of Z is given as, Z = Molar mass n × 96 , 485 To determine: The reason behind the absence of + 1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time.
The reason behind the absence of + 1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time is to be stated. Concept introduction: The non-spontaneous reaction takes place in an electrolytic cell in which there occurs conversion of electrical energy into chemical energy and this is used for the electrolysis of a metal. The charge generated in the cell is calculated as, Q = I t When electricity is passed through an electrolytic cell, at that time the amount of the substance that is liberated at an electrode is given by, W = Z Q = Z I t The value of Z is given as, Z = Molar mass n × 96 , 485 To determine: The reason behind the absence of + 1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time.
Solution Summary: The author explains that the non-spontaneous reaction takes place in an electrolytic cell in which there occurs conversion of electrical energy into chemical energy and this is used for the electrolysis of a metal.
Definition Definition Study of chemical reactions that result in the production of electrical energy. Electrochemistry focuses particularly on how chemical energy is converted into electrical energy and vice-versa. This energy is used in various kinds of cells, batteries, and appliances. Most electrochemical reactions involve oxidation and reduction.
Chapter 17, Problem 130AE
Interpretation Introduction
Interpretation:
The reason behind the absence of
+1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time is to be stated.
Concept introduction:
The non-spontaneous reaction takes place in an electrolytic cell in which there occurs conversion of electrical energy into chemical energy and this is used for the electrolysis of a metal.
The charge generated in the cell is calculated as,
Q=It
When electricity is passed through an electrolytic cell, at that time the amount of the substance that is liberated at an electrode is given by,
W=ZQ=ZIt
The value of
Z is given as,
Z=Molarmassn×96,485
To determine: The reason behind the absence of
+1 charge over the given metal for a given amount of metal that is deposited when a given amount of current is passed for a certain period of time.
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Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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