The standard Gibbs free energy ( Δ G ο ) and the value of equilibrium constant ( K ) for the given reactions are to be calculated at 25 ο C . Concept introduction: Gibbs free energy is a thermodynamic quantity that is used to calculate the maximum work of reversible reaction performed by a system. It is equal to the difference between the enthalpy and the product of entropy at absolute temperature. Equilibrium constant is defined as the ratio of the concentration of products and the concentration of the reactants. To determine: The standard Gibbs free energy ( Δ G ο ) and the value of equilibrium constant ( K ) for the given reaction at 25 ο C .
The standard Gibbs free energy ( Δ G ο ) and the value of equilibrium constant ( K ) for the given reactions are to be calculated at 25 ο C . Concept introduction: Gibbs free energy is a thermodynamic quantity that is used to calculate the maximum work of reversible reaction performed by a system. It is equal to the difference between the enthalpy and the product of entropy at absolute temperature. Equilibrium constant is defined as the ratio of the concentration of products and the concentration of the reactants. To determine: The standard Gibbs free energy ( Δ G ο ) and the value of equilibrium constant ( K ) for the given reaction at 25 ο C .
Solution Summary: The author explains that Gibbs free energy is a thermodynamic quantity that is used to calculate the maximum work of reversible reaction performed by the system.
Science that deals with the amount of energy transferred from one equilibrium state to another equilibrium state.
Chapter 17, Problem 76E
(a)
Interpretation Introduction
Interpretation: The standard Gibbs free energy
(ΔGο) and the value of equilibrium constant
(K) for the given reactions are to be calculated at
25 οC.
Concept introduction: Gibbs free energy is a thermodynamic quantity that is used to calculate the maximum work of reversible reaction performed by a system. It is equal to the difference between the enthalpy and the product of entropy at absolute temperature. Equilibrium constant is defined as the ratio of the concentration of products and the concentration of the reactants.
To determine: The standard Gibbs free energy
(ΔGο) and the value of equilibrium constant
(K) for the given reaction at
25 οC.
(b)
Interpretation Introduction
Interpretation: The standard Gibbs free energy
(ΔGο) and the value of equilibrium constant
(K) for the given reactions are to be calculated at
25 οC.
Concept introduction: Gibbs free energy is a thermodynamic quantity that is used to calculate the maximum work of reversible reaction performed by a system. It is equal to the difference between the enthalpy and the product of entropy at absolute temperature. Equilibrium constant is defined as the ratio of the concentration of products and the concentration of the reactants.
To determine: The standard Gibbs free energy
(ΔGο) and the value of equilibrium constant
(K) for the given reaction at
25 οC.
Given a 1,3-dicarbonyl compound (R1-CO-CH2-CO-R2), indicate the formula of the compound obtaineda) if I add hydroxylamine (NH2OH) to give an isooxazole.b) if I add thiosemicarbazide (NH2-CO-NH-NH2) to give an isothiazole.
An orange laser has a wavelength of 610 nm. What is the energy of this light?
The molar absorptivity of a protein in water at 280 nm can be estimated within ~5-10% from its content of the amino acids tyrosine and tryptophan and from the number of disulfide linkages (R-S-S-R) between cysteine residues:
Ε280 nm (M-1 cm-1) ≈ 5500 nTrp + 1490 nTyr + 125 nS-S
where nTrp is the number of tryptophans, nTyr is the number of tyrosines, and nS-S is the number of disulfide linkages. The protein human serum transferrin has 678 amino acids including 8 tryptophans, 26 tyrosines, and 19 disulfide linkages. The molecular mass of the most dominant for is 79550.
Predict the molar absorptivity of transferrin.
Predict the absorbance of a solution that’s 1.000 g/L transferrin in a 1.000-cm-pathlength cuvet.
Estimate the g/L of a transferrin solution with an absorbance of 1.50 at 280 nm.
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