The reaction taking place in a galvanic cell is given. The identity of the unknown metal used in combination with Aluminum for the construction of given galvanic cell is to be stated. Concept introduction: The galvanic cell converts chemical energy into electrical energy while the electrolytic cell converts electrical energy into chemical energy. The species at anode undergoes oxidation, while the species at cathode undergoes reduction and the electrons generated at the anode are transferred through wire to the cathode. The relationship between cell potential and Gibbs free energy change is given by the formula, Δ G ° = − n F E ° cell To determine: The identity of the unknown metal used in combination with Aluminum for the construction of the given galvanic cell.
The reaction taking place in a galvanic cell is given. The identity of the unknown metal used in combination with Aluminum for the construction of given galvanic cell is to be stated. Concept introduction: The galvanic cell converts chemical energy into electrical energy while the electrolytic cell converts electrical energy into chemical energy. The species at anode undergoes oxidation, while the species at cathode undergoes reduction and the electrons generated at the anode are transferred through wire to the cathode. The relationship between cell potential and Gibbs free energy change is given by the formula, Δ G ° = − n F E ° cell To determine: The identity of the unknown metal used in combination with Aluminum for the construction of the given galvanic cell.
Solution Summary: The author explains the reaction taking place in a galvanic cell and the identity of the unknown metal used in combination with Aluminum.
Interpretation: The reaction taking place in a galvanic cell is given. The identity of the unknown metal used in combination with Aluminum for the construction of given galvanic cell is to be stated.
Concept introduction: The galvanic cell converts chemical energy into electrical energy while the electrolytic cell converts electrical energy into chemical energy.
The species at anode undergoes oxidation, while the species at cathode undergoes reduction and the electrons generated at the anode are transferred through wire to the cathode.
The relationship between cell potential and Gibbs free energy change is given by the formula,
ΔG°=−nFE°cell
To determine: The identity of the unknown metal used in combination with Aluminum for the construction of the given galvanic cell.
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Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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