Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 17, Problem 38P
18-41 Complete these examples of Fischer esterification. In each case, assume an excess of the alcohol.
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B 1 of 2
Additional problems in preparation to Midterm #1:
1.) How can the following compounds be prepared using Diels-Alder reaction:
CH3 O
CN
(a)
(b)
CN
CH3
2.) What is the missing reagent in the shown reaction?
H3C
+ ?
H3C
H3C
CN
H3C
''CN
(၁)
H
3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene.
Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen.
4.) In the shown reaction, which will be the kinetic product and which will be the
thermodynamic product?
H3C
CI
H3C
HCI
H3C
+
5.) Which of the following molecules is aromatic?
(a)
(b)
(c)
H
6.) Which of the following molecules is aromatic?
(a)
(b)
(c)
7.) Write the mechanism for the shown reaction.
+
Ха
AICI 3
CI
8.) Suggest reagents that would convert benzene into the shown compounds.
CI
NO2
-8-6-6-8-a
(a)
(b)
(c)
(d)
(e)
(a)
SO3H
Br
The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;
Chapter 17 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 17.2 - Prob. 17.1QCCh. 17.5 - Prob. 17.2QCCh. 17.5 - Prob. 17.3QCCh. 17 - 18-4 Answer true or false. (a) The functional...Ch. 17 - Prob. 2PCh. 17 - 18-6 Name and draw structural formulas for the...Ch. 17 - 18-7 Write the IUPAC name for each carboxylic...Ch. 17 - 18-8 Write the IUPAC name for each carboxylic...Ch. 17 - Prob. 6PCh. 17 - Prob. 7P
Ch. 17 - Prob. 8PCh. 17 - Prob. 9PCh. 17 - Prob. 10PCh. 17 - 18-14 Answer true or false. (a) Carboxylic acids...Ch. 17 - 18-15 Draw a structural formula for the dimer...Ch. 17 - 18-16 Propanedioic (malonic) acid forms an...Ch. 17 - 18-17 Hexanoic (caproic) acid has a solubility in...Ch. 17 - 18-18 Propanoic acid and methyl acetate are...Ch. 17 - 18-19 The following compounds have approximately...Ch. 17 - Prob. 17PCh. 17 - Prob. 18PCh. 17 - Prob. 19PCh. 17 - 18-23 Characterize the structural features...Ch. 17 - Prob. 21PCh. 17 - Prob. 22PCh. 17 - 18-26 Answer true or false. (a) Carboxylic acids...Ch. 17 - Prob. 24PCh. 17 - 18-28 Arrange these compounds in order of...Ch. 17 - 18-29 Complete the equations for these acid—base...Ch. 17 - 18-30 Complete the equations for these acid-base...Ch. 17 - 18-31 Formic acid is one of the components...Ch. 17 - Prob. 29PCh. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - Prob. 33PCh. 17 - Prob. 34PCh. 17 - 18-38 Which is the stronger base: CH3CH2NH2 or...Ch. 17 - Prob. 36PCh. 17 - Prob. 37PCh. 17 - 18-41 Complete these examples of Fischer...Ch. 17 - Prob. 39PCh. 17 - Prob. 40PCh. 17 - Prob. 41PCh. 17 - Prob. 42PCh. 17 - 18-46 Procaine (its hydrochloride salt is marketed...Ch. 17 - 18-47 Methylparaben and propylparaben are used as...Ch. 17 - 18-48 4-Aminobenzoic acid is prepared from benzoic...Ch. 17 - Prob. 46PCh. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - Prob. 52P
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