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(a)
Interpretation:
Whether the statement.
The general name of an aliphatic
Concept Introduction:
Alkanoic acid is the IUPAC name of carboxylic acid.
- First choose the longest continuous chain of carbon atoms having carboxyl group known as parent chain.
- The numbering of parent chain should be done in a way that the carboxyl group and substituents get the lowest number.
- The root name of the carbon chain is “oic” acid.
- The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
- The alkyl groups are written in alphabetical order.
(b)
Interpretation:
Whether the statement.
A molecule containing two COOH groups is called a dicarboxylic acid is true or false.
Concept Introduction:
Carboxylic acids containing two COOH groups are known as dicarboxylic acid.
(c)
Interpretation:
Whether the statement.
Ethanedioic (oxalic acid) acid is the simplest dicarboxylic acid is true or false.
Concept Introduction:
Oxalic acid contains total two carbon atoms. It’s IUPAC name is ethanedioic acid, here dioic represents the two carboxyl groups.
(d)
Interpretation:
Whether the statement.
3-Methylbutanoic acid is chiral is true or false.
Concept Introduction:
Chiral molecules are those in which there are four different groups attached tetrahedrally.
(e)
Interpretation:
Whether the statement.
The simplest carboxylic acid is methanoic acid (common name: formic acid), HCOOH is true or false.
Concept Introduction:
Formic acid is a carboxylic acid with one carbon.
(f)
Interpretation:
Whether the statement.
Benzoic acid is an
Concept Introduction:
Aromatic carboxylic acid must follow
(g)
Interpretation:
Whether the statement.
Formic acid, which is the common name for HCO2 H, is derived from the word Formica, which is the Latin name for ants is true or false.
Concept Introduction:
Formic acid is a carboxylic acid with one carbon.
(h)
Interpretation:
Whether the statement.
(S)-Lactic acid, CH3 -CHOH-COOH, contains two functional groups: a 20 alcohol and a carboxyl group are true or false.
Concept Introduction:
Lactic acid is 2-hydroxypropanoic acid.
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Chapter 17 Solutions
Introduction To General, Organic, And Biochemistry
- 3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). CN + En CNarrow_forward3) Propagation of uncertainty. Every measurement has uncertainty. In this problem, we'll evaluate the uncertainty in every step of a titration of potassium hydrogen phthalate (a common acid used in titrations, abbreviated KHP, formula CsH5KO4) with NaOH of an unknown concentration. The calculation that ultimately needs to be carried out is: concentration NaOH 1000 x mass KHP × purity KHP molar mass KHP x volume NaOH Measurements: a) You use a balance to weigh 0.3992 g of KHP. The uncertainty is ±0.15 mg (0.00015 g). b) You use a buret to slowly add NaOH to the KHP until it reaches the endpoint. It takes 18.73 mL of NaOH. The uncertainty of the burst is 0.03 mL.. c) The manufacturer states the purity of KHP is 100%±0.05%. d) Even though we don't think much about them, molar masses have uncertainty as well. The uncertainty comes from the distribution of isotopes, rather than random measurement error. The uncertainty in the elements composing KHP are: a. Carbon: b. Hydrogen: ±0.0008…arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- How would you use infrared spectroscopy to distinguish between the following pairs of constitutional isomers? (a) CH3C=CCH3 || and CH3CH2C=CH (b) CH3CCH=CHCH3 and CH3CCH2CH=CH2 Problem 12-41 The mass spectrum (a) and the infrared spectrum (b) of an unknown hydrocarbon are shown. Propose as many structures as you can. (a) 100 Relative abundance (%) 80 60 60 40 200 20 (b) 100 Transmittance (%) 10 20 20 80- 60- 40- 20 40 60 80 100 120 140 m/z 500 4000 3500 3000 2500 2000 1500 Wavenumber (cm-1) 1000arrow_forwardPropagation of uncertainty. You have a stock solution certified by the manufacturer to contain 150.0±0.03 µg SO42-/mL. You would like to dilute it by a factor of 100 to obtain 1.500 µg/mL. Calculate the uncertainty in the two methods of dilution below. Use the following uncertainty values for glassware: Glassware Uncertainty (assume glassware has been calibrated and treat the values below as random error) 1.00 mL volumetric pipet 0.01 mL 10.00 mL volumetric pipet 0.02 mL 100.00 mL volumetric flask 0.08 mL Transfer 10.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask. Then take 10.00 mL of the resulting solution and dilute it a second time with a 100 mL flask. 2. Transfer 1.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask.arrow_forwardDraw all resonance structures for the following ion: CH₂ Draw all resonance structures on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars, including charges where needed. The single bond is active by default. 2D ד CONT HD EXP CON ? 1 [1] Α 12 Marvin JS by Chemaxon A DOO H C N Br I UZ OSPFarrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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