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(a)
Interpretation:The equilibrium expression of
Concept introduction: Heterogeneous equilibrium can be defined as equilibrium where the components (reactants and products) are present in different phases.
(a)
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Answer to Problem 27A
The equilibrium expression is
Explanation of Solution
Equilibrium expressions used to determine the changes in concentration that happens as the reaction approaches equilibrium. Aqueous solutions and gases change their concentrations considerably during the course of reaction. On the other hand, pure liquids and solids do not change their concentration much as reaction moves towards equilibrium since they are present in large excess.
Hence pure liquids and solids are not included in equilibrium expression equation.
The reaction is:
The equilibrium expression is
(b)
Interpretation: The equilibrium expression of heterogeneous equilibrium needs to be determined.
Concept introduction: Heterogeneous equilibrium can be defined as equilibrium where the components (reactants and products) are present in different phases.
(b)
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Answer to Problem 27A
The equilibrium expression is
Explanation of Solution
Equilibrium expressions used to determine the changes in concentration that happens as the reaction approaches equilibrium. Aqueous solutions and gases change their concentrations considerably during the course of reaction. On the other hand, pure liquids and solids do not change their concentration much as reaction moves towards equilibrium since they are present in large excess.
Hence pure liquids and solids are not included in equilibrium expression equation.
The reaction is:
The equilibrium expression is
(c)
Interpretation: The equilibrium expression of heterogeneous equilibrium needs to be determined.
Concept introduction: Heterogeneous equilibrium can be defined as equilibrium where the components (reactants and products) are present in different phases.
(c)

Answer to Problem 27A
The equilibrium expression is
Explanation of Solution
Equilibrium expressions used to determine the changes in concentration that happens as the reaction approaches equilibrium. Aqueous solutions and gases change their concentrations considerably during the course of reaction. On the other hand, pure liquids and solids do not change their concentration much as reaction moves towards equilibrium since they are present in large excess.
Hence pure liquids and solids are not included in equilibrium expression equation.
The reaction is:
The equilibrium expression is
Chapter 17 Solutions
World of Chemistry, 3rd edition
- A doctor gives a patient 10 Ci of beta radiation. How many betaparticles would the patient receive in 1 minute? (1 Ci = 3.7 x 1010d/s)arrow_forwardPart C IN H N. Br₂ (2 equiv.) AlBr3 Draw the molecule on the canvas by choosing buttons from the Tools (for bonds and + e (×) H± 12D T EXP. L CONT. דarrow_forward9. OA. Rank the expected boiling points of the compounds shown below from highest to lowest. Place your answer appropriately in the box. Only the answer in the box will be graded. (3) points) OH OH بر بد بدید 2 3arrow_forward
- There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…arrow_forwardA mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ Marrow_forwardWhat units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?arrow_forward
- Provide the structure, circle or draw, of the monomeric unit found in the biological polymeric materials given below. HO OH amylose OH OH 행 3 HO cellulose OH OH OH Ho HOarrow_forwardWhat units (if any) does K have? Does K depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)? in calculating the response factorarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Don't used Ai solution and don't used hand raitingarrow_forwardOA. For the structure shown, rank the bond lengths (labeled a, b and c) from shortest to longest. Place your answer in the box. Only the answer in the box will be graded. (2 points) H -CH3 THe b Нarrow_forwardDon't used hand raitingarrow_forward
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