Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 17, Problem 25E
Interpretation Introduction
Interpretation:
The explanation for “like dissolves like” and magnitude for each solution has to be discussed.
Concept Introduction:
The bond formed by the atoms which have different electronegativities and have a large dipole moment are known as polar solvents.
For example: water
The bonds which are formed by the atoms which have same electronegativities are known as non-polar solvents.
For example: gasoline, hexane etc.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 17 Solutions
Chemical Principles
Ch. 17 - Prob. 1DQCh. 17 - Consider Fig. 17.8. Suppose that instead of having...Ch. 17 - Prob. 3DQCh. 17 - Prob. 4DQCh. 17 - Prob. 5DQCh. 17 - Prob. 6DQCh. 17 - Prob. 7DQCh. 17 - Prob. 8DQCh. 17 - Prob. 9DQCh. 17 - Prob. 10DQ
Ch. 17 - Prob. 11DQCh. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - Prob. 14ECh. 17 - Prob. 15ECh. 17 - Prob. 16ECh. 17 - Prob. 17ECh. 17 - Prob. 18ECh. 17 - Prob. 19ECh. 17 - Prob. 20ECh. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - Prob. 23ECh. 17 - Prob. 24ECh. 17 - Prob. 25ECh. 17 - Prob. 26ECh. 17 - Prob. 27ECh. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Prob. 34ECh. 17 - Prob. 35ECh. 17 - Prob. 36ECh. 17 - Prob. 37ECh. 17 - Prob. 38ECh. 17 - Prob. 39ECh. 17 - Prob. 40ECh. 17 - Rationalize the temperature dependence of the...Ch. 17 - Prob. 42ECh. 17 - Prob. 43ECh. 17 - Prob. 44ECh. 17 - Prob. 45ECh. 17 - Prob. 46ECh. 17 - Prob. 47ECh. 17 - Prob. 48ECh. 17 - Prob. 49ECh. 17 - Prob. 50ECh. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - The following plot shows the vapor pressure of...Ch. 17 - Prob. 58ECh. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - Prob. 63ECh. 17 - Prob. 64ECh. 17 - Prob. 65ECh. 17 - Prob. 66ECh. 17 - Prob. 67ECh. 17 - An aqueous solution of 10.00 g of catalase, an...Ch. 17 - Prob. 69ECh. 17 - What volume of ethylene glycol (C2H6O2) , a...Ch. 17 - Prob. 71ECh. 17 - Erythrocytes are red blood cells containing...Ch. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - Prob. 77ECh. 17 - Prob. 78ECh. 17 - Prob. 79ECh. 17 - Prob. 80ECh. 17 - Consider the following solutions: 0.010 m Na3PO4...Ch. 17 - From the following: pure water solution of...Ch. 17 - Prob. 83ECh. 17 - Prob. 84ECh. 17 - Prob. 85ECh. 17 - Prob. 86ECh. 17 - Prob. 87ECh. 17 - Prob. 88ECh. 17 - Prob. 89ECh. 17 - Prob. 90ECh. 17 - Prob. 91ECh. 17 - Prob. 92ECh. 17 - Prob. 93AECh. 17 - Prob. 94AECh. 17 - Prob. 95AECh. 17 - Prob. 96AECh. 17 - The term proof is defined as twice the percent by...Ch. 17 - Prob. 98AECh. 17 - Prob. 99AECh. 17 - Prob. 100AECh. 17 - Prob. 101AECh. 17 - Prob. 102AECh. 17 - Prob. 103AECh. 17 - Prob. 104AECh. 17 - Prob. 105AECh. 17 - Prob. 106AECh. 17 - Prob. 107AECh. 17 - Prob. 108AECh. 17 - Prob. 109AECh. 17 - Prob. 110AECh. 17 - Prob. 111AECh. 17 - Prob. 112AECh. 17 - Prob. 113AECh. 17 - Prob. 114AECh. 17 - Formic acid (HCO2H) is a monoprotic acid that...Ch. 17 - Prob. 116AECh. 17 - Prob. 117AECh. 17 - Prob. 118AECh. 17 - Prob. 119AECh. 17 - Prob. 120AECh. 17 - Prob. 121AECh. 17 - Prob. 122AECh. 17 - Prob. 123AECh. 17 - Prob. 124AECh. 17 - Prob. 125AECh. 17 - Prob. 126AECh. 17 - Prob. 127CPCh. 17 - Prob. 128CPCh. 17 - Prob. 129CPCh. 17 - Plants that thrive in salt water must have...Ch. 17 - Prob. 131CPCh. 17 - Prob. 132CPCh. 17 - Prob. 133CPCh. 17 - Prob. 134CPCh. 17 - Prob. 135CPCh. 17 - Prob. 136CP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY