Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 16.8, Problem 9P
Interpretation Introduction

Interpretation:

The pairs of alcohols and acyl chlorides or acid anhydrides that can be used for the synthesis for the given esters are to be identified.

Concept introduction:

The ester is the organic compound derived from the carboxylic acid where a hydroxyl group atom in the carboxylic group is replaced by an alkoxy group.

The esters can be obtained by the reaction of alcohol with acyl chloride or acid anhydride.

In ester, the oxygen that is attached to the carbonyl carbon by a single bond comes from alcohol and the carbonyl group comes from acyl chloride or acid anhydride.

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Draw the structures of the products from the hydrolysis of each of the following with NaOHNaOH.
Explain why carboxylic acids do not undergo nucleophilic acyl substitution reactions with amines.
In biochemical reactions, decarboxylation of carboxylic acids typically takes place for-keto carboxylic acids. Justify a rational why nature opted for-keto carboxylic acid decarboxylation. Among the following types of biochemical reactions, ester hydrolysis, rearrangement reactions, water elimination reactions, and anhydride hydrolyses, which one is the most favorable one. Rank the above reactions types in the order of being the most to least favorable reaction

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