A synthesis for the given compounds using the given starting materials is to be outlined. Concept Introduction: Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly. Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides. Bromine is a good leaving group and can be substituted by conjugate base of H 2 S to form alkane thiols.

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Answer 1

Question

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

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Answer 2

Question

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

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Answer 3

Question

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

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Answer 4

Question

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

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Answer 5

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

Answer 6

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

Answer 7

Chapter 16.12, Problem 15P

Interpretation Introduction

Interpretation:

A synthesis for the given compounds using the given starting materials is to be outlined.

Concept Introduction:

Alcohols contain hydroxyl group, which is not a good leaving group. Therefore, alcohols do not show substitution reactions directly.

Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

Bromine is a good leaving group and can be substituted by conjugate base of H2S to form alkane thiols.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 16.2 - Prob. 1P Ch. 16.2 - Prob. 2P Ch. 16.4 - Prob. 3P Ch. 16.5 - Prob. 4P Ch. 16.5 - Give the structures, including stereochemistry,...Ch. 16.5 - Prob. 6P Ch. 16.7 - Prob. 7P Ch. 16.8 - Prob. 8P Ch. 16.8 - Prob. 9P Ch. 16.9 - Predict the principal organic product of each of...

Solution Summary: The author explains that alcohols contain hydroxyl group, which is not a good leaving group. Alcohols upon reaction with phosphorus tribromide are converted into alkyl bromides.

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