A chemical test that would permit to distinguish between the two glycerol monobenzyl ethers is to be suggested. Concept Introduction: Vicinal diols have a hydroxyl group attached to adjacent carbon atoms. Reaction of a vicinal diol with periodic acid cleaves the bond attached to the two hydroxyl groups. If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom. If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom. If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom. If the compound is a diol, but the hydroxyl groups are not attached to adjacent carbon atoms, then this diol has no effect on it when treated with periodic acid.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 35P

Interpretation Introduction

Interpretation:

A chemical test that would permit to distinguish between the two glycerol monobenzyl ethers is to be suggested.

Concept Introduction:

Vicinal diols have a hydroxyl group attached to adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid cleaves the bond attached to the two hydroxyl groups.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

If the compound is a diol, but the hydroxyl groups are not attached to adjacent carbon atoms, then this diol has no effect on it when treated with periodic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Assign all the protons

PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 35P

Interpretation Introduction

Interpretation:

A chemical test that would permit to distinguish between the two glycerol monobenzyl ethers is to be suggested.

Concept Introduction:

Vicinal diols have a hydroxyl group attached to adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid cleaves the bond attached to the two hydroxyl groups.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

If the compound is a diol, but the hydroxyl groups are not attached to adjacent carbon atoms, then this diol has no effect on it when treated with periodic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 35P

Interpretation Introduction

Interpretation:

A chemical test that would permit to distinguish between the two glycerol monobenzyl ethers is to be suggested.

Concept Introduction:

Vicinal diols have a hydroxyl group attached to adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid cleaves the bond attached to the two hydroxyl groups.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

If the compound is a diol, but the hydroxyl groups are not attached to adjacent carbon atoms, then this diol has no effect on it when treated with periodic acid.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 35P

Interpretation Introduction