Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 16, Problem 39P
Interpretation Introduction

Interpretation:

The structure of the compound having molecular formula C3H7ClO2 on the basis of its 13C NMR spectrum is to be determined.

Concept introduction:

In 13C NMR, a separate peak is observed for each distinct carbon atom.

The number of signals in a spectrum gives information about the type of carbon atoms present in the structure of the compound.

In 13C NMR, the chemical shift depends on the electronegativity of the group attached to carbon atom and the hybridization of the carbon atom.

The electronegative atom/group decreases the shielding of the carbon atom to which it is attached.

Index of hydrogen deficiency (IHD) is calculated by the equation as follows:

IHD=12(CnH2n+2-CnHx)

Here, CnHx is the molecular formula of the compound.

Oxygen atoms do not disturb the index of hydrogen deficiency.

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