The products formed on oxidation of each of the given compounds with periodic acid are to be predicted. Concept Introduction: Vicinal diols are the compounds that have a hydroxyl group attached to the adjacent carbon atoms. Reaction of a vicinal diol with periodic acid results in the cleavage of bonds that connect the two hydroxyl groups to the adjacent carbon atoms in the diol molecule. Depending on the number of hydrogen atoms attached to these carbon atoms, aldehydes or ketones are produced. If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom. If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom. If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16.11, Problem 13P

Interpretation Introduction

Interpretation:

The products formed on oxidation of each of the given compounds with periodic acid are to be predicted.

Concept Introduction:

Vicinal diols are the compounds that have a hydroxyl group attached to the adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid results in the cleavage of bonds that connect the two hydroxyl groups to the adjacent carbon atoms in the diol molecule.

Depending on the number of hydrogen atoms attached to these carbon atoms, aldehydes or ketones are produced.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16.11, Problem 13P

Interpretation Introduction

Interpretation:

The products formed on oxidation of each of the given compounds with periodic acid are to be predicted.

Concept Introduction:

Vicinal diols are the compounds that have a hydroxyl group attached to the adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid results in the cleavage of bonds that connect the two hydroxyl groups to the adjacent carbon atoms in the diol molecule.

Depending on the number of hydrogen atoms attached to these carbon atoms, aldehydes or ketones are produced.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16.11, Problem 13P

Interpretation Introduction

Interpretation:

The products formed on oxidation of each of the given compounds with periodic acid are to be predicted.

Concept Introduction:

Vicinal diols are the compounds that have a hydroxyl group attached to the adjacent carbon atoms.

Reaction of a vicinal diol with periodic acid results in the cleavage of bonds that connect the two hydroxyl groups to the adjacent carbon atoms in the diol molecule.

Depending on the number of hydrogen atoms attached to these carbon atoms, aldehydes or ketones are produced.

If the hydroxyl group is attached to a primary carbon atom, formaldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a secondary carbon atom, aldehyde is produced at that carbon atom.

If the hydroxyl group is attached to a tertiary carbon atom, a ketone is produced at that carbon atom.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16.11, Problem 13P

Interpretation Introduction