Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 16.2, Problem 1P
Interpretation Introduction

Interpretation:

Isomers of alcohol having a molecular formula C4H10O that can be prepared from the reduction of aldehydes and ketones respectively are to be determined. The isomeric form of the same alcohol that cannot be prepared form the reduction of any carbonyl compound is to be identified.

Concept introduction:

The isomers are associated with the same chemical formula but have different connectivity of atoms.

The aldehyde or ketone on hydrogenation undergoes addition of hydrogen across the carbon-oxygen double bond and forms corresponding alcohol.

Hydrogenation is basically the reduction process. The primary alcohol is obtained after reduction of aldehydes, the ketones on reduction gave secondary alcohol but no carbonyl compound gave tertiary alcohol after the reduction process.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Chapter 16 Solutions

Organic Chemistry - Standalone book

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