Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 16, Problem 22P
Interpretation Introduction
Interpretation:
A brief synthesis of each of the given compounds from the indicated starting material and any other necessary organic or inorganic reagents is to be outlined.
Concept introduction:
Alcohols can be prepared from a variety of reagents.
Reaction of Grignard reagents with carbonyl compounds produces the corresponding alcohols.
Grignard reagents also react with oxiranes to produce alcohols.
The allylic and benzylic carbon atoms are selectively brominated using NBS reagent.
Alcohols undergo dehydration in acidic medium producing
Thiols are prepared by the nucleophilic substitution reaction by using the conjugate base of
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A student claims the right-hand side of the reaction in the drawing area below shows the product of a Claisen condensation.
• If the student is correct, complete the reaction by adding the necessary organic reactants to the left-hand side, and by adding any necessary reagents and
reaction conditions above and below the arrow.
• If the student is incorrect, because it's not possible to obtain this product from a Claisen condensation, check the box under the drawing area instead.
those that will minimize any byproducts or competing
• Note for advanced students: If you have a choice, use the most efficient reactants and reagents
reactions.
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The right-hand side of this reaction shows the product of an aldol condensation. What are the reactants missing from the left-hand side? Draw them below.
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NaOH
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If there aren't any reactants that would lead to these products under the reaction conditions given, just check the box under the drawing area.
Note for advanced students: don't worry if the reactants you propose might also make some other products under these reaction conditions. Just make sure the
product above is one of the major products.
Chapter 16 Solutions
Organic Chemistry - Standalone book
Ch. 16.2 - Prob. 1PCh. 16.2 - Prob. 2PCh. 16.4 - Prob. 3PCh. 16.5 - Prob. 4PCh. 16.5 - Give the structures, including stereochemistry,...Ch. 16.5 - Prob. 6PCh. 16.7 - Prob. 7PCh. 16.8 - Prob. 8PCh. 16.8 - Prob. 9PCh. 16.9 - Predict the principal organic product of each of...
Ch. 16.9 - Prob. 11PCh. 16.10 - Prob. 12PCh. 16.11 - Prob. 13PCh. 16.12 - Prob. 14PCh. 16.12 - Prob. 15PCh. 16 - Write chemical equations, showing all necessary...Ch. 16 - Write chemical equations, showing all necessary...Ch. 16 - Which of the isomeric C5H12O alcohols can be...Ch. 16 - Prob. 19PCh. 16 - Write equations showing how 1-phenylethanol could...Ch. 16 - Write equations showing how 2-phenylethanol could...Ch. 16 - Prob. 22PCh. 16 - Show how each of the following compounds can be...Ch. 16 - Prob. 24PCh. 16 - Write the structure of the principal organic...Ch. 16 - Prob. 26PCh. 16 - Prob. 27PCh. 16 - Prob. 28PCh. 16 - Prob. 29PCh. 16 - Prob. 30PCh. 16 - (a) The cis isomer of 3-hexen-1-ol...Ch. 16 - Prob. 32PCh. 16 - Complete each of the following equations by...Ch. 16 - Prob. 34PCh. 16 - Prob. 35PCh. 16 - A diol (C8H18O2) does not react with periodic...Ch. 16 - Identify the compound C8H10O on the basis of its...Ch. 16 - dentify each of the following C4H10O isomers on...Ch. 16 - Prob. 39PCh. 16 - A compound C6H14O has the spectrum shown in Figure...Ch. 16 - Prob. 41DSPCh. 16 - Prob. 42DSPCh. 16 - Prob. 43DSPCh. 16 - Prob. 44DSPCh. 16 - Prob. 45DSPCh. 16 - Prob. 46DSPCh. 16 - Prob. 47DSP
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