THERMODYNAMICS (LL)-W/ACCESS >CUSTOM<
9th Edition
ISBN: 9781266657610
Author: CENGEL
Publisher: MCG CUSTOM
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Chapter 16.6, Problem 40P
(a)
To determine
The amount of heat transfer for the dissociation of Oxygen is
(b)
To determine
The amount of heat transfer for the absence of dissociation of Oxygen.
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An iron-carbon alloy initially containing 0.240 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1100°C. Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0.0 wt% C. At what position will the carbon concentration be 0.180 wt% after a 7 h treatment? The value of D at 1100°C is 3.7 × 10-11 m2/s.
An iron-carbon alloy initially containing 0.268 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1040°C.
Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the
carbon concentration at the surface position is maintained essentially at 0.0 wt% C. At what position will the carbon concentration
be 0.201 wt% after a 7 h treatment? The value of D at 1040°C is 2.5 × 10-¹1 m²/s.
erf(z)
erf(z)
0.55 0.5633 1.3
0.025 0.0282 0.60 0.6039 1.4 0.9523
0.0564 0.65 0.6420 1.5
Z
0.00
0.05
0.15
0.0000
0.10 0.1125 0.70 0.6778
0.20
Z
0.1680 0.75 0.7112 1.7
0.2227 0.80 0.7421 1.8
0.45 0.4755 1.1
0.50 0.5205
Z
1.6
1.2 0.9103
erf(z)
0.9340
2.8
0.9661
0.25 0.2763 0.85 0.7707 1.9 0.9928
0.30 0.3286 0.90 0.7970
2.0 0.9953
0.35 0.3794 0.95 0.8209 2.2
0.40 0.4284 1.0
0.8427 2.4
0.9763
0.9838
0.9891
0.9981
0.8802 2.6 0.9998
0.9993
0.9999
The Ostwald process is used commercially to produce nitric acid, which is, in turn, used in many modern chemical processes. In the first step of the Ostwald process, ammonia is reacted with oxygen gas to produce nitric oxide and water.
What is the maximum mass of H2OH2O that can be produced by combining 79.3 g79.3 g of each reactant?
4NH3(g)+5O2(g)⟶4NO(g)+6H2O(g)
Chapter 16 Solutions
THERMODYNAMICS (LL)-W/ACCESS >CUSTOM<
Ch. 16.6 - Why is the criterion for chemical equilibrium...Ch. 16.6 - Write three different KPrelations for reacting...Ch. 16.6 - Is a wooden table in chemical equilibrium with the...Ch. 16.6 - A reaction chamber contains a mixture of CO2, CO,...Ch. 16.6 - A reaction chamber contains a mixture of N2and N...Ch. 16.6 - A reaction chamber contains a mixture of CO2, CO,...Ch. 16.6 - Which element is more likely to dissociate into...Ch. 16.6 - Prob. 8PCh. 16.6 - Prob. 9PCh. 16.6 - Prob. 10P
Ch. 16.6 - Prob. 11PCh. 16.6 - Prob. 12PCh. 16.6 - Prob. 13PCh. 16.6 - Prob. 14PCh. 16.6 - Prob. 15PCh. 16.6 - Prob. 16PCh. 16.6 - Prob. 17PCh. 16.6 - Prob. 18PCh. 16.6 - Prob. 19PCh. 16.6 - Prob. 20PCh. 16.6 - Prob. 21PCh. 16.6 - Prob. 22PCh. 16.6 - Prob. 23PCh. 16.6 - Determine the equilibrium constant KP for the...Ch. 16.6 - Prob. 26PCh. 16.6 - Prob. 27PCh. 16.6 - Carbon monoxide is burned with 100 percent excess...Ch. 16.6 - Prob. 30PCh. 16.6 - Prob. 31PCh. 16.6 - Estimate KP for the following equilibrium reaction...Ch. 16.6 - Prob. 33PCh. 16.6 - A mixture of 3 mol of N2, 1 mol of O2, and 0.1 mol...Ch. 16.6 - Prob. 35PCh. 16.6 - Prob. 36PCh. 16.6 - Prob. 37PCh. 16.6 - Prob. 38PCh. 16.6 - Prob. 40PCh. 16.6 - What is the equilibrium criterion for systems that...Ch. 16.6 - Prob. 43PCh. 16.6 - Prob. 44PCh. 16.6 - Prob. 45PCh. 16.6 - Prob. 47PCh. 16.6 - Prob. 48PCh. 16.6 - Prob. 51PCh. 16.6 - Prob. 52PCh. 16.6 - Prob. 53PCh. 16.6 - Prob. 54PCh. 16.6 - Prob. 55PCh. 16.6 - Prob. 56PCh. 16.6 - Prob. 58PCh. 16.6 - Prob. 59PCh. 16.6 - Prob. 60PCh. 16.6 - Prob. 61PCh. 16.6 - Using the Henrys constant data for a gas dissolved...Ch. 16.6 - Prob. 63PCh. 16.6 - Prob. 64PCh. 16.6 - Prob. 65PCh. 16.6 - Prob. 66PCh. 16.6 - A liquid-vapor mixture of refrigerant-134a is at...Ch. 16.6 - Prob. 68PCh. 16.6 - Prob. 69PCh. 16.6 - An oxygennitrogen mixture consists of 30 kg of...Ch. 16.6 - Prob. 71PCh. 16.6 - Prob. 72PCh. 16.6 - Prob. 73PCh. 16.6 - Prob. 74PCh. 16.6 - Prob. 75PCh. 16.6 - Prob. 76PCh. 16.6 - An ammoniawater absorption refrigeration unit...Ch. 16.6 - Prob. 78PCh. 16.6 - Prob. 79PCh. 16.6 - Prob. 80PCh. 16.6 - One lbmol of refrigerant-134a is mixed with 1...Ch. 16.6 - Prob. 82RPCh. 16.6 - Prob. 83RPCh. 16.6 - Prob. 84RPCh. 16.6 - Prob. 85RPCh. 16.6 - Prob. 88RPCh. 16.6 - Prob. 89RPCh. 16.6 - Prob. 90RPCh. 16.6 - Prob. 91RPCh. 16.6 - Prob. 92RPCh. 16.6 - A constant-volume tank contains a mixture of 1 mol...Ch. 16.6 - Prob. 94RPCh. 16.6 - Prob. 95RPCh. 16.6 - Prob. 96RPCh. 16.6 - Prob. 97RPCh. 16.6 - Prob. 99RPCh. 16.6 - Consider a glass of water in a room at 25C and 100...Ch. 16.6 - Prob. 101RPCh. 16.6 - Prob. 102RPCh. 16.6 - Prob. 105RPCh. 16.6 - Prob. 106RPCh. 16.6 - Prob. 107RPCh. 16.6 - Prob. 108RPCh. 16.6 - Prob. 109FEPCh. 16.6 - Prob. 110FEPCh. 16.6 - Prob. 111FEPCh. 16.6 - Prob. 112FEPCh. 16.6 - Prob. 113FEPCh. 16.6 - Prob. 114FEPCh. 16.6 - Propane C3H8 is burned with air, and the...Ch. 16.6 - Prob. 116FEPCh. 16.6 - Prob. 117FEPCh. 16.6 - The solubility of nitrogen gas in rubber at 25C is...
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