Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 16.2, Problem 3PPC
Interpretation Introduction
Interpretation:
From the given models, the model representing acid and base has to be identified
Though the formula units of given models are similar they differ in their properties has to be explained.
Concept Information:
The strength of oxoacids can be determined based on the following factors:
- Electronegativity of the central
atom - Oxidation number of the central atom
- Polarity of bond
- Bond enthalpy
- Bond strength
Factors determining strength of oxoacids:
- The polarity and bond strength determines the strength of acids.
Polarity depends on the electronegativities of the atoms involved in bonding. Higher electronegativity leads to higher polarity.
- Higher the polarity, stronger will be the acid.
- Stronger the bond strength, weaker will be the acid.
- The strength of acids having the same central atom but differ in the number of attached oxygen atom depends on the oxidation number of the central atom
- Higher the oxidation number of the central atom, the stronger the acid is.
- Lower oxidation number of the central atom, results in weaker acid
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Chapter 2:
ange over time? If setpoints can change over time, what is this called?
IS water a polar or non-polar molecule? Are polar or non-polar molecules more likely to be soluble in water? How does
the structure of a water molecule contribute to the properties of water as a solvent (e.g. it is polar, it takes a lot of heat to
change the temperature, etc.)?
Compare and contrast the composition, structure, and functions of the four major groups of biomolecules. Which
monomers are used to make polymers in each group (except lipids)? Be able to identify molecules from each group based
on chemical structure (e.g.carbohydrate, nucleotide, phospholipid, amino acid, etc.)
List the important functions of soluble proteins in the body.
What is the law of mass action? Consider the chemical reaction A + B → AB. If we add more of substance A, what will
happen to the amount of substance B and AB?
What is an equilibrium constant (Keg)?
Describe how the binding of a ligand to a protein is regulated…
9* Fill
in the table below. The answers are binary,
Compounds. The Possible responses may in include
more than one existing compounds. The correct answer
will be the compound where the least Electronegative
element is in it's highest Oxidation State.
Reactions of nonmetals with other' nonmetals
Group HA (C)
Halogens
(F₂, Cl₂, B1₂, 5₂)
* Selec*
Oxygen (0₂) Carbonate Jon
Carbon monoxide
Carbon tetraoxide
Carbon
dioxide
Select
Carbon tribromide
Carbon tetrachloride
Carbon diflouride
Carbon moniodide
Group 5A (P)
* Select *
Phosphorus trioxide
diphosphorus tetraoxide
tetraphosphorus decaoxide
Phosphorus Pentaoxide
* Select *
diphosphorus trichloride
Phosphorus tribromide
Phosphorus Penta fluoride
Phosphorus diiodide
Group 6A(s)
Select
Sulfur dioxide
disulful penta oxide
Sulfut monoxide
Sulfur trioxide
Select
sulfur hexafluoride
Sulfur tetra fluoride
Sulfur difluoride
the cyanide ion reacts with hydrochloric acid. explain why the H+ ion favor one atom in the polyatomic ion versus the other.
Chapter 16 Solutions
Chemistry: Atoms First
Ch. 16.1 - What is (a) the conjugate base of HNO3, (b) the...Ch. 16.1 - What is (a) the conjugate acid of ClO4, (b) the...Ch. 16.1 - HSO3 is the conjugate acid of what species? HSO3...Ch. 16.1 - Which of the models represents a species that has...Ch. 16.1 - Prob. 16.2WECh. 16.1 - Identify and label the species in each reaction....Ch. 16.1 - Prob. 2PPBCh. 16.1 - Write the formula and charge for each species in...Ch. 16.1 - Prob. 16.1.1SRCh. 16.1 - Prob. 16.1.2SR
Ch. 16.2 - Predict the relative strengths of the oxoacids in...Ch. 16.2 - Prob. 3PPACh. 16.2 - Based on the information in this section, which is...Ch. 16.2 - Prob. 3PPCCh. 16.2 - Prob. 16.2.1SRCh. 16.2 - Prob. 16.2.2SRCh. 16.2 - Prob. 16.2.3SRCh. 16.3 - Prob. 16.4WECh. 16.3 - The concentration of hydroxide ions in the antacid...Ch. 16.3 - The value of Kw at normal body temperature (37C)...Ch. 16.3 - Prob. 4PPCCh. 16.3 - Prob. 16.3.1SRCh. 16.3 - Prob. 16.3.2SRCh. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Prob. 5PPCCh. 16.4 - Calculate the hydroxide ion concentration in a...Ch. 16.4 - Prob. 6PPACh. 16.4 - Prob. 6PPBCh. 16.4 - Prob. 6PPCCh. 16.4 - Prob. 16.4.1SRCh. 16.4 - Prob. 16.4.2SRCh. 16.4 - Prob. 16.4.3SRCh. 16.4 - Prob. 16.4.4SRCh. 16.5 - Calculate the pH of an aqueous solution at 25C...Ch. 16.5 - Prob. 7PPACh. 16.5 - Prob. 7PPBCh. 16.5 - Prob. 7PPCCh. 16.5 - Prob. 16.8WECh. 16.5 - Calculate the concentration of HNO3 in a solution...Ch. 16.5 - Prob. 8PPBCh. 16.5 - Which of the plots [(i)(iv)] best approximates the...Ch. 16.5 - Prob. 16.9WECh. 16.5 - Prob. 9PPACh. 16.5 - Prob. 9PPBCh. 16.5 - Prob. 9PPCCh. 16.5 - Prob. 16.10WECh. 16.5 - Prob. 10PPACh. 16.5 - Prob. 10PPBCh. 16.5 - Prob. 10PPCCh. 16.5 - Prob. 16.5.1SRCh. 16.5 - Prob. 16.5.2SRCh. 16.5 - Prob. 16.5.3SRCh. 16.5 - Prob. 16.5.4SRCh. 16.5 - Prob. 16.5.5SRCh. 16.5 - Prob. 16.5.6SRCh. 16.5 - Prob. 16.5.7SRCh. 16.6 - The Ka of hypochlorous acid (HClO) is 3.5 108....Ch. 16.6 - Calculate the pH at 25C of a 0.18-M solution of a...Ch. 16.6 - Prob. 11PPBCh. 16.6 - The diagrams show solutions of four different weak...Ch. 16.6 - Determine the pH and percent ionization for acetic...Ch. 16.6 - Determine the pH and percent ionization for...Ch. 16.6 - At what concentration does hydrocyanic acid...Ch. 16.6 - Prob. 12PPCCh. 16.6 - Aspirin (acetylsalicylie acid, HC9H7O4) is a weak...Ch. 16.6 - Prob. 13PPACh. 16.6 - Prob. 13PPBCh. 16.6 - Calculate Ka values (to two significant figures)...Ch. 16.6 - Prob. 16.6.1SRCh. 16.6 - Prob. 16.6.2SRCh. 16.6 - Prob. 16.6.3SRCh. 16.7 - Prob. 16.14WECh. 16.7 - Calculate the pH at 25C of a 0.0028-M solution of...Ch. 16.7 - Prob. 14PPBCh. 16.7 - The diagrams represent solutions of three...Ch. 16.7 - Caffeine, the stimulant in coffee and tea, is a...Ch. 16.7 - Prob. 15PPACh. 16.7 - Prob. 15PPBCh. 16.7 - Prob. 15PPCCh. 16.7 - Prob. 16.7.1SRCh. 16.7 - Prob. 16.7.2SRCh. 16.7 - Prob. 16.7.3SRCh. 16.8 - Prob. 16.16WECh. 16.8 - Prob. 16PPACh. 16.8 - Prob. 16PPBCh. 16.8 - Prob. 16PPCCh. 16.8 - Prob. 16.8.1SRCh. 16.8 - Prob. 16.8.2SRCh. 16.8 - Prob. 16.8.3SRCh. 16.9 - Oxalic acid (H2C2O4) is a poisonous substance used...Ch. 16.9 - Calculate the concentrations of H2C2O4, HC2O4,...Ch. 16.9 - Calculate the concentrations of H2SO4, HSO4, SO42,...Ch. 16.9 - Prob. 17PPCCh. 16.9 - Prob. 16.9.1SRCh. 16.9 - Prob. 16.9.2SRCh. 16.9 - Prob. 16.9.3SRCh. 16.10 - Prob. 16.18WECh. 16.10 - Determine the pH of a 0.15-M solution of sodium...Ch. 16.10 - Prob. 18PPBCh. 16.10 - Winch of the graphs [(i)(iv)] best represents the...Ch. 16.10 - Calculate the pH of a 0.10-M solution of ammonium...Ch. 16.10 - Determine the pH of a 0.25-M solution of...Ch. 16.10 - Prob. 19PPBCh. 16.10 - Prob. 19PPCCh. 16.10 - Predict whether a 0.10-M solution of each of the...Ch. 16.10 - Predict whether a 0.10-M solution of each of the...Ch. 16.10 - Prob. 20PPBCh. 16.10 - Prob. 20PPCCh. 16.10 - Prob. 16.10.1SRCh. 16.10 - Prob. 16.10.2SRCh. 16.10 - Prob. 16.10.3SRCh. 16.10 - Prob. 16.10.4SRCh. 16.10 - Prob. 16.10.5SRCh. 16.12 - Identify the Lewis acid and Lewis base in each of...Ch. 16.12 - Prob. 21PPACh. 16.12 - Prob. 21PPBCh. 16.12 - Which of the diagrams best depicts the combination...Ch. 16.12 - Prob. 16.12.1SRCh. 16.12 - Prob. 16.12.2SRCh. 16 - F or a species to act as a Brnsted base, an atom...Ch. 16 - Identify the acid-base conjugate pairs in each of...Ch. 16 - Prob. 16.3QPCh. 16 - Prob. 16.4QPCh. 16 - Write the formulas of the conjugate bases of the...Ch. 16 - Prob. 16.6QPCh. 16 - Prob. 16.7QPCh. 16 - List four factors that affect the strength of an...Ch. 16 - Prob. 16.9QPCh. 16 - Prob. 16.10QPCh. 16 - Prob. 16.11QPCh. 16 - Prob. 16.12QPCh. 16 - Prob. 16.13QPCh. 16 - Write the equilibrium expression for the...Ch. 16 - Write an equation relating [H+] and [OH] in...Ch. 16 - Write an equation relating [H+] and [OH] in...Ch. 16 - Prob. 16.17QPCh. 16 - Prob. 16.18QPCh. 16 - Prob. 16.19QPCh. 16 - Prob. 16.20QPCh. 16 - Prob. 16.21QPCh. 16 - Prob. 16.22QPCh. 16 - Prob. 16.23QPCh. 16 - Calculate the concentration of H+ ions in a 0.62 M...Ch. 16 - Calculate the concentration of OH ions in a 1.4 ...Ch. 16 - Calculate the pH of each of the following...Ch. 16 - Calculate the pH of each of the following...Ch. 16 - Prob. 16.28QPCh. 16 - Prob. 16.29QPCh. 16 - Prob. 16.30QPCh. 16 - How much NaOH (in grams) is needed to prepare 546...Ch. 16 - Prob. 16.32QPCh. 16 - Why are ionizations of strong acids and strong...Ch. 16 - Prob. 16.34QPCh. 16 - Prob. 16.35QPCh. 16 - Prob. 16.36QPCh. 16 - Prob. 16.37QPCh. 16 - Prob. 16.38QPCh. 16 - Prob. 16.39QPCh. 16 - Prob. 16.40QPCh. 16 - Prob. 16.41QPCh. 16 - Prob. 16.42QPCh. 16 - Prob. 16.43QPCh. 16 - Prob. 16.1VCCh. 16 - Prob. 16.2VCCh. 16 - Prob. 16.3VCCh. 16 - Prob. 16.4VCCh. 16 - Prob. 16.44QPCh. 16 - Prob. 16.45QPCh. 16 - Prob. 16.46QPCh. 16 - Why do we normally not quote Ka values for strong...Ch. 16 - Why is it necessary to specify temperature when...Ch. 16 - Which of the following solutions has the highest...Ch. 16 - Prob. 16.50QPCh. 16 - The Ka for benzoic acid is 6.5 105. Calculate the...Ch. 16 - Calculate the pH of an aqueous solution at 25C...Ch. 16 - Calculate the pH of an aqueous solution at 25C...Ch. 16 - Determine the percent ionization of the following...Ch. 16 - Determine the percent ionization of the following...Ch. 16 - Prob. 16.56QPCh. 16 - A 0.015-M solution of a monoprotic acid is 0.92%...Ch. 16 - Prob. 16.58QPCh. 16 - Prob. 16.59QPCh. 16 - Prob. 16.60QPCh. 16 - Prob. 16.61QPCh. 16 - Prob. 16.62QPCh. 16 - In biological and medical applications, it is...Ch. 16 - Classify each of the following species as a weak...Ch. 16 - Prob. 16.65QPCh. 16 - Prob. 16.66QPCh. 16 - Prob. 16.67QPCh. 16 - Which of the following has a higher pH: (a) 1.0 M...Ch. 16 - Prob. 16.69QPCh. 16 - Prob. 16.70QPCh. 16 - Prob. 16.71QPCh. 16 - What is the original molarity of an aqueous...Ch. 16 - Prob. 16.73QPCh. 16 - Prob. 16.74QPCh. 16 - Prob. 16.75QPCh. 16 - Prob. 16.76QPCh. 16 - Prob. 16.77QPCh. 16 - Calculate Ka for each of the following ions: NH4+,...Ch. 16 - The following diagrams represent aqueous solutions...Ch. 16 - Prob. 16.80QPCh. 16 - Write all the species (except water) that are...Ch. 16 - Write the Ka1 and Ka2 expressions for sulfurous...Ch. 16 - Prob. 16.83QPCh. 16 - Prob. 16.84QPCh. 16 - Prob. 16.85QPCh. 16 - Prob. 16.86QPCh. 16 - Calculate the pH at 25C of a 0.25-M aqueous...Ch. 16 - The first and second ionization constants of a...Ch. 16 - Prob. 16.89QPCh. 16 - Prob. 16.90QPCh. 16 - Explain why small, highly charged metal ions are...Ch. 16 - Prob. 16.92QPCh. 16 - Specify which of the following salts will undergo...Ch. 16 - Prob. 16.94QPCh. 16 - Calculate the pH of a 0.42 M NH4Cl solution. (Kb...Ch. 16 - Calculate the pH of a 0.082 M NaF solution. (Ka...Ch. 16 - Calculate the pH of a 0.91 M C2H5NH3I solution....Ch. 16 - Prob. 16.98QPCh. 16 - Predict whether the following solutions are...Ch. 16 - Prob. 16.100QPCh. 16 - In a certain experiment, a student finds that the...Ch. 16 - Prob. 16.102QPCh. 16 - Prob. 16.103QPCh. 16 - Classify the following oxides as acidic, basic,...Ch. 16 - Prob. 16.105QPCh. 16 - Explain why metal oxides tend to be basic if the...Ch. 16 - Arrange the oxides in each of the following groups...Ch. 16 - Prob. 16.108QPCh. 16 - Prob. 16.109QPCh. 16 - Prob. 16.110QPCh. 16 - Prob. 16.111QPCh. 16 - Prob. 16.112QPCh. 16 - In terms of orbitals and electron arrangements,...Ch. 16 - Prob. 16.114QPCh. 16 - Prob. 16.115QPCh. 16 - Which would be considered a stronger Lewis acid:...Ch. 16 - Prob. 16.117QPCh. 16 - Identify the Lewis acid and the Lewis base in the...Ch. 16 - Identify the Lewis acid and the Lewis base in the...Ch. 16 - Prob. 16.120QPCh. 16 - Prob. 16.121QPCh. 16 - Prob. 16.122QPCh. 16 - Prob. 16.123QPCh. 16 - Prob. 16.124QPCh. 16 - Calculate the pH and percent ionization of a 0.88...Ch. 16 - Prob. 16.126QPCh. 16 - Prob. 16.127QPCh. 16 - The pH of a 0.0642-M solution of a monoprotic acid...Ch. 16 - Prob. 16.129QPCh. 16 - HA and HB are both weak acids although HB is the...Ch. 16 - Prob. 16.131QPCh. 16 - Prob. 16.132QPCh. 16 - Use the data in Table 16.5 to calculate the...Ch. 16 - Prob. 16.134QPCh. 16 - Most of the hydrides of Group 1A and Group 2 A...Ch. 16 - Prob. 16.136QPCh. 16 - Novocaine, used as a local anesthetic by dentists,...Ch. 16 - Which of the following is the stronger base: NF3...Ch. 16 - Prob. 16.139QPCh. 16 - The ion product of D20 is 1.35 1015 at 25C. (a)...Ch. 16 - Prob. 16.141QPCh. 16 - Prob. 16.142QPCh. 16 - Prob. 16.143QPCh. 16 - Prob. 16.144QPCh. 16 - Prob. 16.145QPCh. 16 - When the concentration of a strong acid is not...Ch. 16 - Calculate the pH of a 2.00 M NH4CN solution.Ch. 16 - Prob. 16.148QPCh. 16 - Prob. 16.149QPCh. 16 - Prob. 16.150QPCh. 16 - Prob. 16.151QPCh. 16 - Hydrocyanic acid (HCN) is a weak acid and a deadly...Ch. 16 - How many grams of NaCN would you need to dissolve...Ch. 16 - Prob. 16.154QPCh. 16 - Calculate the pH of a 1-L solution containing...Ch. 16 - Prob. 16.156QPCh. 16 - You are given two beakers, one containing an...Ch. 16 - Use Le Chteliers principle to predict the effect...Ch. 16 - A 0.400 M formic acid (HCOOH) solution freezes at...Ch. 16 - The disagreeable odor of fish is mainly due to...Ch. 16 - Prob. 16.161QPCh. 16 - Prob. 16.162QPCh. 16 - Both the amide ion (NH2) and the nitride ion (N3)...Ch. 16 - When carbon dioxide is bubbled through a clear...Ch. 16 - Explain the action of smelling salt, which is...Ch. 16 - About half of the hydrochloric acid produced...Ch. 16 - Which of the following does not represent a Lewis...Ch. 16 - Determine whether each of the following statements...Ch. 16 - How many milliliters of a strong monoprotic acid...Ch. 16 - Hemoglobin (Hb) is a blood protein that is...Ch. 16 - Prob. 16.171QPCh. 16 - Calculate the pH of a solution that is 1.00 M HCN...Ch. 16 - Tooth enamel is largely hydroxyapatite...Ch. 16 - Prob. 16.174QPCh. 16 - Prob. 16.175QPCh. 16 - Prob. 16.176QPCh. 16 - Sulfuric acid (H2SO4) accounts for as much as 80...Ch. 16 - A 1-87-g sample of Mg reacts with 80.0 mL of a HCl...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - Determine pH at the equivalence point in the...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - Determine pH at the equivalence point in the...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Fill in the name and empirical formula of each ionic compound that could be formed from the ions in this table?arrow_forwardLook at the structure of a soap molecule, and explain what happened when you added soap to your oily hands and put your hands under the water for the solubility lab. Why could you wash the oil off your hands with soap and water? You should use chemistry concepts including structure, polarity, and intermolecular forces to explain your answer. attached is the lewis structure of a basic soap molecule. There are covalent bonds between all carbons, hydrogens, and oxygens. However, there is an ionic bond between oxygen and sodium ions.arrow_forwardCompare the chemical structure of compound A with that of compound B. Answer it in a detailed way. Thank You.arrow_forward
- compound hydrogen-bonding force Between Between molecules of formula or Lewis molecules of the the compound and molecules of water? name structure compound? H H | Н — С | | yes yes N-chloromethylamine - no no H. yes yes hydrogen iodide HI no no :0: || н —с —с-о — н H yes yes acetic acid no no H O Oarrow_forwardX is a metal. The physical properties of metal X will be different after atom X reacts with chlorine atom and form compound XCl. Distinguish between the physical properties of metal X and XCI compound.arrow_forward6. ptic Complete the table below as shown by the example. Combine the ions into a corect formula, and name the compound. acetate ion dichromate ion bydroxide ion NH4C2H3O2 ammoniur ion ammonium acetate cadmium ion lead(IV) ion Identifying Anions in Solution 100arrow_forward
- Write a Lewis symbol for atom or ion. S2-arrow_forwardConsider these compounds: A. BaSO4 . B. PbCrO4 C. Cr(OH)3 D. Ag3PO4 Complete the following statements by entering the letter(s) corresponding to the correct compound(s). (If more than one compound fits the description, include all the relevant compounds by writing your answer as a string of characters without punctuation, e.g, ABC.) Without doing any calculations it is possible to determine that silver bromide is more soluble than bromide is less soluble than It is not possible to determine whether silver bromide is more or less soluble than [ Submit Answer Retry Entire Group 9 more group attempts remaining and silver by simply comparing Kp values.arrow_forward2a. Determine the theoretical lattice energy using the Kapustinskii's equation. 1.202 x 105 VZ*Z¯ U = 34.5 r* + r r* + r Ca2+ = 114 pm I = 206 pm b. Compare your answer to the experimental lattice energy of -1971 kJ/mol.arrow_forward
- Citric acid (abbreviated H3Cit) is a triprotic acid, so 3 moles of hydroxide ions are required per mole of citric acid for complete neutralization. A.) Write the balanced chemical equation for the reaction of citric acid with sodium hydroxide. (Note that citrate ion is actually a polyatomic ion with carbon, hydrogen, and oxygen atoms and an overall charge of −3. For now, express citrate ion as Cit3−.) B.) If 36.10 mL of 0.223 M NaOH is used to neutralize a 0.515 g sample of citric acid, what is the molar mass (in g/mol) of the acid?arrow_forwardgroup A solutions: Conductivity (ms) concentration of chloride ions: NaCl 6594 0.19 CaCl2 13188 0.6 AlCl3 16311 0.9 Why do the Group A compounds, each with the same concentration (0.05 M), have such large differences in conductivity values?arrow_forwardThe molecular structure of ibuprofen, a widely used pain reliever. Ibuprofen has a limited solubility to water, less than 1mg/mL. Identify which part of the molecule contributes to its water solubility and water insolubility.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY