Phenol is found to be stronger than methanol and this difference has to be explained. Concept Introduction: Bronsted's definition is based on the chemical reaction that occurs when both acids and bases are added with each other. In Bronsted's theory acid donates proton, while base accepts proton from acid. When Bronsted base accepts a proton the protonated species is known as conjugate acid and when Bronsted acid loses a proton the deprotonated species is known as conjugate base . The strength of the Bronsted acid is determined by the stability of the conjugate base that is formed from it. If there is possibility of resonance stabilization in the formed conjugate base then that will be more strong acid. To Explain: Why phenol is more acidic than methanol.
Phenol is found to be stronger than methanol and this difference has to be explained. Concept Introduction: Bronsted's definition is based on the chemical reaction that occurs when both acids and bases are added with each other. In Bronsted's theory acid donates proton, while base accepts proton from acid. When Bronsted base accepts a proton the protonated species is known as conjugate acid and when Bronsted acid loses a proton the deprotonated species is known as conjugate base . The strength of the Bronsted acid is determined by the stability of the conjugate base that is formed from it. If there is possibility of resonance stabilization in the formed conjugate base then that will be more strong acid. To Explain: Why phenol is more acidic than methanol.
Solution Summary: The author explains that Phenol is stronger than methanol due to the resonance stabilized conjugate base formed from phenol.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 16, Problem 16.13QP
Interpretation Introduction
Interpretation: Phenol is found to be stronger than methanol and this difference has to be explained.
Concept Introduction:
Bronsted's definition is based on the chemical reaction that occurs when both acids and bases are added with each other. In Bronsted's theory acid donates proton, while base accepts proton from acid.
When Bronsted base accepts a proton the protonated species is known as conjugate acid and when Bronsted acid loses a proton the deprotonated species is known as conjugate base.
The strength of the Bronsted acid is determined by the stability of the conjugate base that is formed from it. If there is possibility of resonance stabilization in the formed conjugate base then that will be more strong acid.
To Explain: Why phenol is more acidic than methanol.
An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
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